The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

Esther Zeigerson; Gregory Ginzburg; Louis J. Kirschenbaum; Dan Meyerstein

doi:10.1016/S0022-0728(81)80472-X

The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

Esther Zeigerson
, Gregory Ginzburg
, Louis J. Kirschenbaum
, Dan Meyerstein

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

33 ציטוטים ‏(Scopus)

תקציר

The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.

שפה מקורית	אנגלית
עמודים (מ-עד)	113-126
מספר עמודים	14
כתב עת	Journal of Electroanalytical Chemistry
כרך	127
מספר גיליון	1-3
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1016/S0022-0728(81)80472-X
סטטוס פרסום	פורסם - 9 אוק׳ 1981
פורסם באופן חיצוני	כן

גישה למסמך

10.1016/S0022-0728(81)80472-X

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

@article{a2fdc3eb484f477bb76ecdbbb4b83ab4,

title = "The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions",

abstract = "The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.",

author = "Esther Zeigerson and Gregory Ginzburg and Kirschenbaum, \{Louis J.\} and Dan Meyerstein",

note = "Funding Information: This study was supported in part by the United States-Israel Binational Science Foundation (B.S.F.) Jerusalem, Israel. A fellowship to E.Z. from the A.K. Casali Foundation is appreciated. Thanks are due to Dr. S. Maniv of the Physics Dept., Ben-Gurion University of the Negev, for preparation of electrodes.",

year = "1981",

month = oct,

day = "9",

doi = "10.1016/S0022-0728(81)80472-X",

language = "אנגלית",

volume = "127",

pages = "113--126",

journal = "Journal of Electroanalytical Chemistry",

issn = "0022-0728",

publisher = "Elsevier B.V.",

number = "1-3",

}

The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions. / Zeigerson, Esther; Ginzburg, Gregory; Kirschenbaum, Louis J. et al.
ב-: Journal of Electroanalytical Chemistry, כרך 127, מס' 1-3, 09.10.1981, עמוד 113-126.

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

TY - JOUR

T1 - The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

AU - Zeigerson, Esther

AU - Ginzburg, Gregory

AU - Kirschenbaum, Louis J.

AU - Meyerstein, Dan

N1 - Funding Information: This study was supported in part by the United States-Israel Binational Science Foundation (B.S.F.) Jerusalem, Israel. A fellowship to E.Z. from the A.K. Casali Foundation is appreciated. Thanks are due to Dr. S. Maniv of the Physics Dept., Ben-Gurion University of the Negev, for preparation of electrodes.

PY - 1981/10/9

Y1 - 1981/10/9

N2 - The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.

AB - The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.

UR - https://www.scopus.com/pages/publications/2542549068

U2 - 10.1016/S0022-0728(81)80472-X

DO - 10.1016/S0022-0728(81)80472-X

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AN - SCOPUS:2542549068

SN - 0022-0728

VL - 127

SP - 113

EP - 126

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1-3

ER -

The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

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