Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H2O)5Cr-CH(CH3)CH(CH3)OH2+

Haim Cohen; Alexander Feldman; Ruth Ish-Shalom; Dan Meyerstein

doi:10.1021/ja00014a023

Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H₂O)₅Cr-CH(CH₃)CH(CH₃)OH²⁺

Haim Cohen
, Alexander Feldman
, Ruth Ish-Shalom
, Dan Meyerstein

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

16 ציטוטים ‏(Scopus)

תקציר

The reaction of the aliphatic free radical *CH(CH₃)CH(OH)CH₃ (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.

שפה מקורית	אנגלית
עמודים (מ-עד)	5292-5299
מספר עמודים	8
כתב עת	Journal of the American Chemical Society
כרך	113
מספר גיליון	14
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1021/ja00014a023
סטטוס פרסום	פורסם - 1 יולי 1991
פורסם באופן חיצוני	כן

גישה למסמך

10.1021/ja00014a023

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

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title = "Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H2O)5Cr-CH(CH3)CH(CH3)OH2+ ",

abstract = "The reaction of the aliphatic free radical *CH(CH3)CH(OH)CH3 (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.",

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Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H₂O)₅Cr-CH(CH₃)CH(CH₃)OH²⁺ . / Cohen, Haim; Feldman, Alexander; Ish-Shalom, Ruth et al.
ב-: Journal of the American Chemical Society, כרך 113, מס' 14, 01.07.1991, עמוד 5292-5299.

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

TY - JOUR

T1 - Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H2O)5Cr-CH(CH3)CH(CH3)OH2+

AU - Cohen, Haim

AU - Feldman, Alexander

AU - Ish-Shalom, Ruth

AU - Meyerstein, Dan

PY - 1991/7/1

Y1 - 1991/7/1

N2 - The reaction of the aliphatic free radical *CH(CH3)CH(OH)CH3 (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.

AB - The reaction of the aliphatic free radical *CH(CH3)CH(OH)CH3 (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.

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