Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Haim Cohen; Shlomo Efrima; Dan Meyerstein; Mordechi Nutkovich; Karl Wieghardt

doi:10.1021/ic00146a023

Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Haim Cohen
, Shlomo Efrima
, Dan Meyerstein
, Mordechi Nutkovich
, Karl Wieghardt

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

4 ציטוטים ‏(Scopus)

תקציר

The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

שפה מקורית	אנגלית
עמודים (מ-עד)	688-690
מספר עמודים	3
כתב עת	Inorganic Chemistry
כרך	22
מספר גיליון	4
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1021/ic00146a023
סטטוס פרסום	פורסם - פבר׳ 1983
פורסם באופן חיצוני	כן

גישה למסמך

10.1021/ic00146a023

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

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title = "Selectivity of Outer-Sphere Electron-Transfer Reactions. 3",

abstract = "The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.",

author = "Haim Cohen and Shlomo Efrima and Dan Meyerstein and Mordechi Nutkovich and Karl Wieghardt",

year = "1983",

month = feb,

doi = "10.1021/ic00146a023",

language = "אנגלית",

volume = "22",

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journal = "Inorganic Chemistry",

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T1 - Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

AU - Cohen, Haim

AU - Efrima, Shlomo

AU - Meyerstein, Dan

AU - Nutkovich, Mordechi

AU - Wieghardt, Karl

PY - 1983/2

Y1 - 1983/2

N2 - The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

AB - The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

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DO - 10.1021/ic00146a023

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AN - SCOPUS:4243547758

SN - 0020-1669

VL - 22

SP - 688

EP - 690

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

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