Reduction of maleate and fumarate by the CO2.- anion radical

Osnat Schutz; Dan Meyerstein

doi:10.1016/j.tetlet.2005.12.042

Reduction of maleate and fumarate by the CO_2.- anion radical

Osnat Schutz
, Dan Meyerstein

מדעי הכימיה

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

12 ציטוטים ‏(Scopus)

תקציר

The radical anion CO₂^.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (^-O₂CCH₂-)₂, trans-( ^-O₂CCH)₂ and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.

שפה מקורית	אנגלית
עמודים (מ-עד)	1093-1096
מספר עמודים	4
כתב עת	Tetrahedron Letters
כרך	47
מספר גיליון	7
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1016/j.tetlet.2005.12.042
סטטוס פרסום	פורסם - 13 פבר׳ 2006

גישה למסמך

10.1016/j.tetlet.2005.12.042

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

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title = "Reduction of maleate and fumarate by the CO2.- anion radical",

abstract = "The radical anion CO2.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (-O2CCH2-)2, trans-( -O2CCH)2 and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.",

author = "Osnat Schutz and Dan Meyerstein",

note = "Funding Information: This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education and the Israel Atomic Energy Commission. D.M. wishes to express his thanks to Mrs. Irene Evans for her ongoing interest and support.",

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doi = "10.1016/j.tetlet.2005.12.042",

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T1 - Reduction of maleate and fumarate by the CO2.- anion radical

AU - Schutz, Osnat

AU - Meyerstein, Dan

N1 - Funding Information: This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education and the Israel Atomic Energy Commission. D.M. wishes to express his thanks to Mrs. Irene Evans for her ongoing interest and support.

PY - 2006/2/13

Y1 - 2006/2/13

N2 - The radical anion CO2.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (-O2CCH2-)2, trans-( -O2CCH)2 and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.

AB - The radical anion CO2.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (-O2CCH2-)2, trans-( -O2CCH)2 and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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