תקציר
This short review discusses recent mechanistic studies concerning the reactions of alkyl radicals with surfaces of metals and semiconductors suspended in aqueous solutions. The results point out that these reactions are fast and involve the formations of transients with -bonds between the radical and the surface. The mechanism of decomposition of the transients thus formed depends on the nature of the surface; the radical; the solvent etc. In reaction with nano-particles supported on semiconductors or on insulators the nature of the support affects dramatically the mechanism of decomposition of these transients. These processes have to be considered in catalytic, electro-chemical, photo-chemical and environmental processes.
שפה מקורית | אנגלית |
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כותר פרסום המארח | The optimization of composition, structure and properties of metals, oxides, composites, nano and amorphous materials |
עמודים | 180-185 |
מספר עמודים | 6 |
סטטוס פרסום | פורסם - 2016 |
אירוע | The Optimization of Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials: Seventh Israeli-Russian Bi-National Workshop 2008 - Perm, רוסיה משך הזמן: 4 אוג׳ 2008 → 11 אוג׳ 2008 מספר ועידה: The Fifteenth Israeli - Russian Bi-National Workshop 2016 |
כנס
כנס | The Optimization of Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials |
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מדינה/אזור | רוסיה |
עיר | Perm |
תקופה | 4/08/08 → 11/08/08 |