TY - JOUR
T1 - Properties of (1,4,7,10,13-penta-azacyclohexadecane)nickel(III) in aqueous solutions
T2 - A pulse radiolytic study
AU - Fabbrizzi, Luigi
AU - Cohen, Hain
AU - Meyerstein, Dan
N1 - Funding Information:
We cannot rule out thepossibility that at very high alkalinity [NiL5(0H)l2+, a six-co-ordinated species, might be formed.IIAcknowledgementsThis work was supported in part by a grant from the U S . -Israel Binational Science Foundation (B.S. F.), Jerusalem.References1 M. Jaacobi, D. Meyerstein, and J . Lllie, tnorg. Chem., 1979, 18,429.2 E. Zeigerson, G. Ginzburg, N. Schwarts, Z. Luz, and D. Meyer-stein, J. Chem. Sot.., Chem. Commun., 1979, 241.3 H. Cohen, L. J. Kirschenbaum, E. Zeigerson, M. Jaacobi, E.Fuchs, G. Ginzburg, and D. Meyerstein, Inorg. Chem., 1979, 18,2763.4 E. Zeigerson, G . Ginzburg, L. J. Kirschenbaum, and D. Meyer-stein, J. Electroanal. Chem. Interfacial Electrochem., 198 1, 127,113.5 E. Zeigerson, G. Ginzburg, J . Becker, L. J. Kirschenbaum, H.Cohen, and D. Meyerstein, tnorg. Chem., 1981, 20, 3988.6 E. Zeigerson, I. Bar, J. Bernstein, L. J. Kirschenbaum, and D.Meyerstein, tnorg. Chem., 1982, 21, 73.7 P. Marathamuthu, L. K. Patterson, and G. Ferraudi, tnorg.Chem., 1978, 17, 3157.8 K. D. Whitburn and G. S. Laurence, J . Chem. Soc., DaltonTrans., 1979, 139.9 L. Fabbrizzi, J. Chem. SOC., Chem. Commun., 1979, 1063.10 P. Morliere and L. K. Patterson, Inorg. Chem., 1981, 20, 1458;1982, 21, 1833, 1837.11 J. Lati and D. Meyerstein, I n t . J . Radiat. Phys. Chem., 1975, 7 ,611; E. Fuchs, H. Cohen, K. Wieghardt, J. Koresh, and D.Meyerstein, unpublished work.12 A. Bencini, L. Fabbrizzi, and A. Poggi, tnorg. Chem., 1981, 20,2544.Received 1 6th December 1982 ; Paper 21209
PY - 1983
Y1 - 1983
N2 - The oxidation of (1,4,7,10,13-penta-azacyclohexadecane)nickel(II) by OH· radicals in aqueous solutions was studied, and the properties of the resulting nickel(III) complex are compared with those of analogous complexes [NiL]3+ where L is a tetra-azacyclotetradecane ligand. The difference in the properties is attributed to the fifth nitrogen donor atom which decreases the acidity of the central tervalent nickel.
AB - The oxidation of (1,4,7,10,13-penta-azacyclohexadecane)nickel(II) by OH· radicals in aqueous solutions was studied, and the properties of the resulting nickel(III) complex are compared with those of analogous complexes [NiL]3+ where L is a tetra-azacyclotetradecane ligand. The difference in the properties is attributed to the fifth nitrogen donor atom which decreases the acidity of the central tervalent nickel.
UR - https://www.scopus.com/pages/publications/37049093818
U2 - 10.1039/DT9830002125
DO - 10.1039/DT9830002125
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AN - SCOPUS:37049093818
SN - 1472-7773
SP - 2125
EP - 2126
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 9
ER -