Physical properties of oxygen-17 water. Absolute viscosity and density of H2 17O between 15 and 35°C

Albert I. Kudish; David Wolf; Fritz Steckel

doi:10.1039/F19747000484

Physical properties of oxygen-17 water. Absolute viscosity and density of H₂ ¹⁷O between 15 and 35°C

Albert I. Kudish
, David Wolf
, Fritz Steckel

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

5 ציטוטים ‏(Scopus)

תקציר

The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100% H ₂ ¹⁷O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53% ¹⁷O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H₂ ¹⁷O relative to natural water. The viscosity ratio at 25°C for H₂ ¹⁷O/H₂ ¹⁶O is 1.0226, whereas that for H ₂ ¹⁸O/H₂ ¹⁶O and D₂ ¹⁶O/H₂ ¹⁶O is 1.0536 and 1.2316, respectively.

שפה מקורית	אנגלית
עמודים (מ-עד)	484-489
מספר עמודים	6
כתב עת	Journal of the Chemical Society, Faraday Transactions I
כרך	70
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1039/F19747000484
סטטוס פרסום	פורסם - 1974
פורסם באופן חיצוני	כן

גישה למסמך

10.1039/F19747000484

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

@article{9043579ae09947dd8aefcc9fa4ae45b3,

title = "Physical properties of oxygen-17 water. Absolute viscosity and density of H2 17O between 15 and 35°C",

abstract = "The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100\% H 2 17O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53\% 17O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H2 17O relative to natural water. The viscosity ratio at 25°C for H2 17O/H2 16O is 1.0226, whereas that for H 2 18O/H2 16O and D2 16O/H2 16O is 1.0536 and 1.2316, respectively.",

author = "Kudish, \{Albert I.\} and David Wolf and Fritz Steckel",

year = "1974",

doi = "10.1039/F19747000484",

language = "אנגלית",

volume = "70",

pages = "484--489",

}

TY - JOUR

T1 - Physical properties of oxygen-17 water. Absolute viscosity and density of H2 17O between 15 and 35°C

AU - Kudish, Albert I.

AU - Wolf, David

AU - Steckel, Fritz

PY - 1974

Y1 - 1974

N2 - The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100% H 2 17O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53% 17O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H2 17O relative to natural water. The viscosity ratio at 25°C for H2 17O/H2 16O is 1.0226, whereas that for H 2 18O/H2 16O and D2 16O/H2 16O is 1.0536 and 1.2316, respectively.

AB - The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100% H 2 17O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53% 17O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H2 17O relative to natural water. The viscosity ratio at 25°C for H2 17O/H2 16O is 1.0226, whereas that for H 2 18O/H2 16O and D2 16O/H2 16O is 1.0536 and 1.2316, respectively.

UR - https://www.scopus.com/pages/publications/0039858847

U2 - 10.1039/F19747000484

DO - 10.1039/F19747000484

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AN - SCOPUS:0039858847

SN - 0300-9599

VL - 70

SP - 484

EP - 489

JO - Journal of the Chemical Society, Faraday Transactions I

JF - Journal of the Chemical Society, Faraday Transactions I