On the reactions of Cu(II/I)ATP complexes with methyl radicals

Ana Lerner; Dan Meyerstein; Alex Blahman; Magal Saphier; Guy Yardeni; Eric Maimon; Haya Kornweitz; Israel Zilbermann

doi:10.1016/j.jinorgbio.2022.111883

On the reactions of Cu(II/I)ATP complexes with methyl radicals

Ana Lerner
, Dan Meyerstein
, Alex Blahman
, Magal Saphier
, Guy Yardeni
, Eric Maimon
, Haya Kornweitz
, Israel Zilbermann

מדעי הכימיה

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

2 ציטוטים ‏(Scopus)

תקציר

The Cu^I/IIATP react with methyl radicals to form methane and methanol, where Cu^IATP reacts with ^•CH₃ in a process that is surprisingly slow. The low-rate constant of this process is attributed to the significant rearrangement of the chelating ligand required for the transient's formation. These results were corroborated by DFT calculations of the relevant compounds.

שפה מקורית	אנגלית
מספר המאמר	111883
כתב עת	Journal of Inorganic Biochemistry
כרך	234
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1016/j.jinorgbio.2022.111883
סטטוס פרסום	פורסם - ספט׳ 2022

גישה למסמך

10.1016/j.jinorgbio.2022.111883

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

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title = "On the reactions of Cu(II/I)ATP complexes with methyl radicals",

abstract = "The CuI/IIATP react with methyl radicals to form methane and methanol, where CuIATP reacts with •CH3 in a process that is surprisingly slow. The low-rate constant of this process is attributed to the significant rearrangement of the chelating ligand required for the transient's formation. These results were corroborated by DFT calculations of the relevant compounds.",

keywords = "Adenosine triphosphate, Copper complexes, DFT, Radicals, Radiolysis, Reaction mechanisms",

author = "Ana Lerner and Dan Meyerstein and Alex Blahman and Magal Saphier and Guy Yardeni and Eric Maimon and Haya Kornweitz and Israel Zilbermann",

note = "Publisher Copyright: {\textcopyright} 2022",

year = "2022",

month = sep,

doi = "10.1016/j.jinorgbio.2022.111883",

language = "אנגלית",

volume = "234",

journal = "Journal of Inorganic Biochemistry",

issn = "0162-0134",

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TY - JOUR

T1 - On the reactions of Cu(II/I)ATP complexes with methyl radicals

AU - Lerner, Ana

AU - Meyerstein, Dan

AU - Blahman, Alex

AU - Saphier, Magal

AU - Yardeni, Guy

AU - Maimon, Eric

AU - Kornweitz, Haya

AU - Zilbermann, Israel

PY - 2022/9

Y1 - 2022/9

N2 - The CuI/IIATP react with methyl radicals to form methane and methanol, where CuIATP reacts with •CH3 in a process that is surprisingly slow. The low-rate constant of this process is attributed to the significant rearrangement of the chelating ligand required for the transient's formation. These results were corroborated by DFT calculations of the relevant compounds.

AB - The CuI/IIATP react with methyl radicals to form methane and methanol, where CuIATP reacts with •CH3 in a process that is surprisingly slow. The low-rate constant of this process is attributed to the significant rearrangement of the chelating ligand required for the transient's formation. These results were corroborated by DFT calculations of the relevant compounds.

KW - Adenosine triphosphate

KW - Copper complexes

KW - DFT

KW - Radicals

KW - Radiolysis

KW - Reaction mechanisms

UR - https://www.scopus.com/pages/publications/85132514003

U2 - 10.1016/j.jinorgbio.2022.111883

DO - 10.1016/j.jinorgbio.2022.111883

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C2 - 35717883

AN - SCOPUS:85132514003

SN - 0162-0134

VL - 234

JO - Journal of Inorganic Biochemistry

JF - Journal of Inorganic Biochemistry

M1 - 111883

ER -

On the reactions of Cu(II/I)ATP complexes with methyl radicals

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