תקציר
Vinyl azides react with boron trifluoride activated Koser's hypervalent iodine reagent to afford azido-enolonium species. These previously unknown azido-enolonium species react efficiently with aromatic compounds, allyltrimethylsilane, and azoles under mild conditions, with no need for a transition-metal catalyst, forming C-C and C-N bonds to give a variety of α-functionalized ketones. The intermediacy of the proposed azido-enolonium species is supported by spectroscopic studies.
| שפה מקורית | אנגלית |
|---|---|
| עמודים (מ-עד) | 768-771 |
| מספר עמודים | 4 |
| כתב עת | Organic Letters |
| כרך | 22 |
| מספר גיליון | 3 |
| מזהי עצם דיגיטלי (DOIs) | |
| סטטוס פרסום | פורסם - 7 פבר׳ 2020 |