β-Hydride shift involvement in the acid catalysed decomposition of [(H2O)5CrIII-C(CH3) 2OH]2+

Nurit Shaham; Haim Cohen; Dan Meyerstein

doi:10.1039/a905674b

β-Hydride shift involvement in the acid catalysed decomposition of [(H₂O)₅Cr^III-C(CH₃) ₂OH]²⁺

Nurit Shaham
, Haim Cohen
, Dan Meyerstein

מדעי הכימיה

פרסום מחקרי: פרסום בכתב עת › מאמר › ביקורת עמיתים

4 ציטוטים ‏(Scopus)

תקציר

Propene has been found to be a major product of the acid catalysed decomposition of [(H₂O)₅Cr^III-C(CH₃) ₂OH]²⁺. It is proposed that this complex isomerizes via a β-hydride shift step to form [(H₂O)₅Cr^III-CH₂CH(CH ₃)OH]²⁺ which decomposes via β-hydroxide elimination.

שפה מקורית	אנגלית
עמודים (מ-עד)	3805-3808
מספר עמודים	4
כתב עת	Journal of the Chemical Society. Dalton Transactions
מספר גיליון	21
מזהי עצם דיגיטלי (DOIs)	https://doi.org/10.1039/a905674b
סטטוס פרסום	פורסם - 7 נוב׳ 1999

גישה למסמך

10.1039/a905674b

קבצים וקישורים אחרים

Link to publication in Scopus

פורמט ציטוט ביבליוגרפי

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title = "β-Hydride shift involvement in the acid catalysed decomposition of [(H2O)5CrIII-C(CH3) 2OH]2+",

abstract = "Propene has been found to be a major product of the acid catalysed decomposition of [(H2O)5CrIII-C(CH3) 2OH]2+. It is proposed that this complex isomerizes via a β-hydride shift step to form [(H2O)5CrIII-CH2CH(CH 3)OH]2+ which decomposes via β-hydroxide elimination.",

author = "Nurit Shaham and Haim Cohen and Dan Meyerstein",

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AU - Shaham, Nurit

AU - Cohen, Haim

AU - Meyerstein, Dan

PY - 1999/11/7

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N2 - Propene has been found to be a major product of the acid catalysed decomposition of [(H2O)5CrIII-C(CH3) 2OH]2+. It is proposed that this complex isomerizes via a β-hydride shift step to form [(H2O)5CrIII-CH2CH(CH 3)OH]2+ which decomposes via β-hydroxide elimination.

AB - Propene has been found to be a major product of the acid catalysed decomposition of [(H2O)5CrIII-C(CH3) 2OH]2+. It is proposed that this complex isomerizes via a β-hydride shift step to form [(H2O)5CrIII-CH2CH(CH 3)OH]2+ which decomposes via β-hydroxide elimination.

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