Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: 2D-ELDOR

Baldev R. Patyal; Richard H. Crepeau; Dan Gamliel; Jack H. Freed

doi:10.1016/0009-2614(90)85563-R

Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: 2D-ELDOR

Baldev R. Patyal, Richard H. Crepeau, Dan Gamliel, Jack H. Freed

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The two-dimensional Fourier transform ESP techniques of stimulated SECSY and 2D-ELDOR are shown to be powerful methods for the study of slow motions for nitroxides. Stimulated SECSY provides magnetization transfer rates, whereas 2D-ELDOR displays how the rotational motions spread the spins out from their initial spectral positions to new spectral positions, as a function of mixing time. The role of nuclear modulation in studies of structure and dynamics is also considered.

Original language	English
Pages (from-to)	453-460
Number of pages	8
Journal	Chemical Physics Letters
Volume	175
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(90)85563-R
State	Published - 21 Dec 1990
Externally published	Yes

Access to Document

10.1016/0009-2614(90)85563-R

Cite this

@article{cdeab9c5df2e496c86235b83a4081afd,

title = "Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: 2D-ELDOR",

abstract = "The two-dimensional Fourier transform ESP techniques of stimulated SECSY and 2D-ELDOR are shown to be powerful methods for the study of slow motions for nitroxides. Stimulated SECSY provides magnetization transfer rates, whereas 2D-ELDOR displays how the rotational motions spread the spins out from their initial spectral positions to new spectral positions, as a function of mixing time. The role of nuclear modulation in studies of structure and dynamics is also considered.",

author = "Patyal, {Baldev R.} and Crepeau, {Richard H.} and Dan Gamliel and Freed, {Jack H.}",

year = "1990",

month = dec,

day = "21",

doi = "10.1016/0009-2614(90)85563-R",

language = "אנגלית",

volume = "175",

pages = "453--460",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "5",

}

TY - JOUR

T1 - Two-dimensional Fourier transform ESR in the slow-motional and rigid limits

T2 - 2D-ELDOR

AU - Patyal, Baldev R.

AU - Crepeau, Richard H.

AU - Gamliel, Dan

AU - Freed, Jack H.

PY - 1990/12/21

Y1 - 1990/12/21

N2 - The two-dimensional Fourier transform ESP techniques of stimulated SECSY and 2D-ELDOR are shown to be powerful methods for the study of slow motions for nitroxides. Stimulated SECSY provides magnetization transfer rates, whereas 2D-ELDOR displays how the rotational motions spread the spins out from their initial spectral positions to new spectral positions, as a function of mixing time. The role of nuclear modulation in studies of structure and dynamics is also considered.

AB - The two-dimensional Fourier transform ESP techniques of stimulated SECSY and 2D-ELDOR are shown to be powerful methods for the study of slow motions for nitroxides. Stimulated SECSY provides magnetization transfer rates, whereas 2D-ELDOR displays how the rotational motions spread the spins out from their initial spectral positions to new spectral positions, as a function of mixing time. The role of nuclear modulation in studies of structure and dynamics is also considered.

UR - http://www.scopus.com/inward/record.url?scp=33646733444&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(90)85563-R

DO - 10.1016/0009-2614(90)85563-R

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:33646733444

SN - 0009-2614

VL - 175

SP - 453

EP - 460

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5

ER -

Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: 2D-ELDOR

Abstract

Access to Document

Other files and links

Fingerprint

Cite this