Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: SECSY-ESR

Baldev R. Patyal; Richard H. Crepeau; Dan Gamliel; Jack H. Freed

doi:10.1016/0009-2614(90)85562-Q

Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: SECSY-ESR

Baldev R. Patyal
, Richard H. Crepeau
, Dan Gamliel
, Jack H. Freed

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Two-dimensional Fourier transform ESR has now been extended to the slow-motional and rigid limit regimes which require spectral bandwidths of 200-250 MHz and sub-nanosecond time resolution in echo decays. Two-pulse SECSY-ESR on nitroxides is shown to provide detailed structural information from the effects of nuclear modulation and slow-motional information from both the main ESR spectrum as well as the nuclear modulation.

Original language	English
Pages (from-to)	445-452
Number of pages	8
Journal	Chemical Physics Letters
Volume	175
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(90)85562-Q
State	Published - 21 Dec 1990
Externally published	Yes

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title = "Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: SECSY-ESR",

abstract = "Two-dimensional Fourier transform ESR has now been extended to the slow-motional and rigid limit regimes which require spectral bandwidths of 200-250 MHz and sub-nanosecond time resolution in echo decays. Two-pulse SECSY-ESR on nitroxides is shown to provide detailed structural information from the effects of nuclear modulation and slow-motional information from both the main ESR spectrum as well as the nuclear modulation.",

author = "Patyal, \{Baldev R.\} and Crepeau, \{Richard H.\} and Dan Gamliel and Freed, \{Jack H.\}",

note = "Funding Information: * Supported by NSF Grant CHE 9004552 and NIH Grant GM25862.",

year = "1990",

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AU - Patyal, Baldev R.

AU - Crepeau, Richard H.

AU - Gamliel, Dan

AU - Freed, Jack H.

N1 - Funding Information: * Supported by NSF Grant CHE 9004552 and NIH Grant GM25862.

PY - 1990/12/21

Y1 - 1990/12/21

N2 - Two-dimensional Fourier transform ESR has now been extended to the slow-motional and rigid limit regimes which require spectral bandwidths of 200-250 MHz and sub-nanosecond time resolution in echo decays. Two-pulse SECSY-ESR on nitroxides is shown to provide detailed structural information from the effects of nuclear modulation and slow-motional information from both the main ESR spectrum as well as the nuclear modulation.

AB - Two-dimensional Fourier transform ESR has now been extended to the slow-motional and rigid limit regimes which require spectral bandwidths of 200-250 MHz and sub-nanosecond time resolution in echo decays. Two-pulse SECSY-ESR on nitroxides is shown to provide detailed structural information from the effects of nuclear modulation and slow-motional information from both the main ESR spectrum as well as the nuclear modulation.

UR - https://www.scopus.com/pages/publications/0011449346

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DO - 10.1016/0009-2614(90)85562-Q

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Two-dimensional Fourier transform ESR in the slow-motional and rigid limits: SECSY-ESR

Abstract

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