Theoretical model and experimental study of pore growth during thermal expansion of graphite intercalation compounds

R. D. Mysyk; G. E. Whyman; M. V. Savoskin; A. P. Yaroshenko

doi:10.1007/s10973-005-0571-3

Theoretical model and experimental study of pore growth during thermal expansion of graphite intercalation compounds

R. D. Mysyk, G. E. Whyman, M. V. Savoskin, A. P. Yaroshenko

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A new technique, which allows one to simultaneously follow the mass and volume of graphite intercalation compounds (GICs) during thermal transformation into expanded graphite, was developed. This enabled us to elucidate the mechanism for the thermal expansion of GICs and formulate a quantitative model for the process. Effective activation parameters of the thermal decomposition of new GICs were obtained by using non-isothermal kinetics procedure. Thermal decomposition was described as a break of intermolecular bonds followed by diffusion.

Original language	English
Pages (from-to)	515-519
Number of pages	5
Journal	Journal of Thermal Analysis and Calorimetry
Volume	79
Issue number	3
DOIs	https://doi.org/10.1007/s10973-005-0571-3
State	Published - Feb 2005
Externally published	Yes

Keywords

Compounds
Graphite intercalation
Micro-pores
Thermal decomposition
Thermal expansion

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10.1007/s10973-005-0571-3

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abstract = "A new technique, which allows one to simultaneously follow the mass and volume of graphite intercalation compounds (GICs) during thermal transformation into expanded graphite, was developed. This enabled us to elucidate the mechanism for the thermal expansion of GICs and formulate a quantitative model for the process. Effective activation parameters of the thermal decomposition of new GICs were obtained by using non-isothermal kinetics procedure. Thermal decomposition was described as a break of intermolecular bonds followed by diffusion.",

keywords = "Compounds, Graphite intercalation, Micro-pores, Thermal decomposition, Thermal expansion",

author = "Mysyk, {R. D.} and Whyman, {G. E.} and Savoskin, {M. V.} and Yaroshenko, {A. P.}",

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KW - Micro-pores

KW - Thermal decomposition

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ER -

Theoretical model and experimental study of pore growth during thermal expansion of graphite intercalation compounds

Abstract

Keywords

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