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The stabilization of monovalent copper ions by complexation with saturated tertiary amine ligands in aqueous solutions. the case of 2,5,9,12-tetramethyl-2, 5,9,12-tetraazatridecane

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Abstract

The complex of copper(I) ions with 2,5,9,12-tetramethyl-2,5,9,12- tetraazatridecane in aqueous solutions is stable in the absence of oxygen; this observation indicates that the stabilization of low valent transition metal cations by tertiary tetraazamacrocylic ligands is due to the hydrophobic nature of these ligands.

Original languageEnglish
Pages (from-to)397-398
Number of pages2
JournalJournal of the Chemical Society D: Chemical Communications
Issue number5
DOIs
StatePublished - 1992
Externally publishedYes

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