The limiting current of electrochemical reaction in the binary electrolyte in the rotating electrochemical cell

D. A. Bograchev, A. D. Davydov

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

A rotating cylindrical electrochemical cell with a plane ring electrode on its cover containing a binary electrolyte was considered. The equation for the diffusion limiting current density on the ring electrode was derived ignoring the effect of Coriolis force. The solution of transfer equations by the Karman method at the limiting current in the cell allowed us to analyze the effect of Coriolis force on the boundary layer thickness and to determine the conditions, under which the Coriolis force may be ignored.

Original languageEnglish
Pages (from-to)1180-1184
Number of pages5
JournalRussian Journal of Electrochemistry
Volume44
Issue number10
DOIs
StatePublished - Oct 2008
Externally publishedYes

Keywords

  • Coriolis force
  • Diffusion limiting current
  • Rotating electrochemical cell
  • The Karman method

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