TY - JOUR
T1 - Syn-(Me,Me)Bimane as a Structural Building Block in Metal Coordination Architectures
AU - Diskin-Posner, Yael
AU - Amer, Sara
AU - Roy, Ankana
AU - Das, Partha Jyoti
AU - Grynszpan, Flavio
AU - Montag, Michael
N1 - Publisher Copyright:
Copyright © 2019 American Chemical Society.
PY - 2019/8/7
Y1 - 2019/8/7
N2 - Li(I) and Na(I) complexes of the fluorescent dye syn-(Me,Me)bimane were isolated and crystallographically characterized, revealing the bimane as a principal component in diverse coordination topologies, including discrete and polymeric structures. The bimane exhibits multiple functions in these frameworks, acting as a variable-denticity O-donor ligand, π-stacking unit, and hydrogen bond acceptor. These features highlight a new role for syn-bimanes, not as fluorophores, but as versatile building blocks in metal coordination architectures.
AB - Li(I) and Na(I) complexes of the fluorescent dye syn-(Me,Me)bimane were isolated and crystallographically characterized, revealing the bimane as a principal component in diverse coordination topologies, including discrete and polymeric structures. The bimane exhibits multiple functions in these frameworks, acting as a variable-denticity O-donor ligand, π-stacking unit, and hydrogen bond acceptor. These features highlight a new role for syn-bimanes, not as fluorophores, but as versatile building blocks in metal coordination architectures.
UR - http://www.scopus.com/inward/record.url?scp=85070892761&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.9b00089
DO - 10.1021/acs.cgd.9b00089
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AN - SCOPUS:85070892761
SN - 1528-7483
VL - 19
SP - 4358
EP - 4368
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 8
ER -