Syn-(Me,Me)Bimane as a Structural Building Block in Metal Coordination Architectures

Yael Diskin-Posner, Sara Amer, Ankana Roy, Partha Jyoti Das, Flavio Grynszpan, Michael Montag

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Li(I) and Na(I) complexes of the fluorescent dye syn-(Me,Me)bimane were isolated and crystallographically characterized, revealing the bimane as a principal component in diverse coordination topologies, including discrete and polymeric structures. The bimane exhibits multiple functions in these frameworks, acting as a variable-denticity O-donor ligand, π-stacking unit, and hydrogen bond acceptor. These features highlight a new role for syn-bimanes, not as fluorophores, but as versatile building blocks in metal coordination architectures.

Original languageEnglish
Pages (from-to)4358-4368
Number of pages11
JournalCrystal Growth and Design
Volume19
Issue number8
DOIs
StatePublished - 7 Aug 2019

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