Sensitive and selective detection of cesium via fluorescence quenching

Bhasker Radaram, Teresa Mako, Mindy Levine

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

Herein we report a robust and easy method for detecting cesium metal ion (Cs+) in partially aqueous solutions using the fluorescence quenching of 2,4-bis[4-(N,N-dihydroxyethylamino)phenyl]squaraine. This squaraine dye was found to be both highly sensitive (low limits of detection) and selective (limited response to other metals) for cesium ion detection. The detection is likely based on the metal complexing to the dihydroxyethanolamine moieties, which disrupts the donor-acceptor-donor architecture and leads to efficient quenching.

Original languageEnglish
Pages (from-to)16276-16278
Number of pages3
JournalDalton Transactions
Volume42
Issue number46
DOIs
StatePublished - 14 Dec 2013
Externally publishedYes

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