Scandium Phosphate Doped with Mn4+

P. P. Mel'nikov; L. C. Ferracin; M. Gaft; L. N. Komissarova

Scandium Phosphate Doped with Mn⁴⁺

P. P. Mel'nikov, L. C. Ferracin, M. Gaft, L. N. Komissarova

Research output: Contribution to journal › Article › peer-review

Abstract

The interaction between manganese dioxide and xenotime-structure ScPO₄ was studied by x-ray diffraction, IR spectroscopy, electron paramagnetic resonance, and luminescence spectroscopy. The results demonstrate that up to 1.5 wt % MnO₂ can be accommodated by ScPO₄ without structural changes. Mn⁴⁺ disproportionates by the reaction Mn⁴⁺ → Mn²⁺ + Mn⁵⁺ and is present in the structure of ScPO₄ in the form of the Mn²⁺ ion, substituting for Sc³⁺, and the MnO₄^3- ion, an analog of PO₄^3-. The presence of Mn³⁺, substituting isovalently for Sc³⁺, also cannot be ruled out. The manganese ions are shown to be rigidly fixed in the structure of ScPO₄.

Original language	English
Pages (from-to)	1010-1013
Number of pages	4
Journal	Inorganic Materials
Volume	34
Issue number	10
State	Published - Oct 1998
Externally published	Yes

Cite this

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title = "Scandium Phosphate Doped with Mn4+",

abstract = "The interaction between manganese dioxide and xenotime-structure ScPO4 was studied by x-ray diffraction, IR spectroscopy, electron paramagnetic resonance, and luminescence spectroscopy. The results demonstrate that up to 1.5 wt % MnO2 can be accommodated by ScPO4 without structural changes. Mn4+ disproportionates by the reaction Mn4+ → Mn2+ + Mn5+ and is present in the structure of ScPO4 in the form of the Mn2+ ion, substituting for Sc3+, and the MnO43- ion, an analog of PO43-. The presence of Mn3+, substituting isovalently for Sc3+, also cannot be ruled out. The manganese ions are shown to be rigidly fixed in the structure of ScPO4.",

author = "Mel'nikov, {P. P.} and Ferracin, {L. C.} and M. Gaft and Komissarova, {L. N.}",

year = "1998",

month = oct,

language = "אנגלית",

volume = "34",

pages = "1010--1013",

journal = "Inorganic Materials",

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publisher = "Pleiades Publishing",

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TY - JOUR

T1 - Scandium Phosphate Doped with Mn4+

AU - Mel'nikov, P. P.

AU - Ferracin, L. C.

AU - Gaft, M.

AU - Komissarova, L. N.

PY - 1998/10

Y1 - 1998/10

N2 - The interaction between manganese dioxide and xenotime-structure ScPO4 was studied by x-ray diffraction, IR spectroscopy, electron paramagnetic resonance, and luminescence spectroscopy. The results demonstrate that up to 1.5 wt % MnO2 can be accommodated by ScPO4 without structural changes. Mn4+ disproportionates by the reaction Mn4+ → Mn2+ + Mn5+ and is present in the structure of ScPO4 in the form of the Mn2+ ion, substituting for Sc3+, and the MnO43- ion, an analog of PO43-. The presence of Mn3+, substituting isovalently for Sc3+, also cannot be ruled out. The manganese ions are shown to be rigidly fixed in the structure of ScPO4.

AB - The interaction between manganese dioxide and xenotime-structure ScPO4 was studied by x-ray diffraction, IR spectroscopy, electron paramagnetic resonance, and luminescence spectroscopy. The results demonstrate that up to 1.5 wt % MnO2 can be accommodated by ScPO4 without structural changes. Mn4+ disproportionates by the reaction Mn4+ → Mn2+ + Mn5+ and is present in the structure of ScPO4 in the form of the Mn2+ ion, substituting for Sc3+, and the MnO43- ion, an analog of PO43-. The presence of Mn3+, substituting isovalently for Sc3+, also cannot be ruled out. The manganese ions are shown to be rigidly fixed in the structure of ScPO4.

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AN - SCOPUS:2542600263

SN - 0020-1685

VL - 34

SP - 1010

EP - 1013

JO - Inorganic Materials

JF - Inorganic Materials

IS - 10

ER -

Scandium Phosphate Doped with Mn⁴⁺

Abstract

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