Revolutionary ZVI-Entrapped Sol–Gel Silica Matrices: Efficient Catalytic Reduction of High-Concentration Halo-Organic Compounds—Addressing Bromoacetic Acid Contamination in Industrial Wastewaters

Gifty Sara Rolly, Dan Meyerstein, Ariela Burg, Dror Shamir, Yael Albo

Research output: Contribution to journalArticlepeer-review

Abstract

The de-halogenation of highly concentrated halo-organic compounds using Zero Valent Iron entrapped in silica matrices as a catalyst was investigated. This study aimed to evaluate the effectiveness of the Zero Valent Iron-entrapped organically modified silica matrices in transforming highly concentrated hazardous halogenated compounds into environmentally benign materials in the presence of BH4. The Zero Valent Iron-entrapped silica gel matrices were synthesized using the sol–gel method. The de-halogenation products were analyzed using high-performance liquid chromatography. The results suggest that the Zero Valent Iron-entrapped silica matrices are effective catalysts in the de-halogenation reaction of halo-organics by BH4 with 100% efficiency. The current work also highlights the complete de-bromination of harmful wastewater generated by the bromoacetic acid manufacturing industry using Zero Valent Iron-entrapped silica matrices. Therefore, Zero Valent Iron-entrapped silica matrices can be considered potential candidates for the catalytic removal of highly concentrated halo-organic compounds from contaminated water. This technology can play a crucial role in reducing the environmental impact of hazardous substances.

Original languageEnglish
Article number718
JournalGels
Volume10
Issue number11
DOIs
StatePublished - Nov 2024

Keywords

  • de-halogenation
  • halo-organic compounds
  • sol–gel
  • wastewater
  • zero-valent iron

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