Reductive and oxidative reactions of calix[4]arene derivatives

Flavio Grynszpan; Nahum Dinoor; Silvio E. Biali

doi:10.1016/S0040-4039(00)85995-X

Reductive and oxidative reactions of calix[4]arene derivatives

Flavio Grynszpan, Nahum Dinoor, Silvio E. Biali

Research output: Contribution to journal › Article › peer-review

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Abstract

Reductive cleavage of 25,26,27,28-tetramethoxy-p-tert-butylcalix[4]arene with K results in the formation of 26,28-dimethoxy-p-t-butylcalix[4]arene. The reaction of 25,27-dihydroxycalix[4]arene with NO₂BF₄ in acetonitrile results in its oxidation to calixdiquinone 6.

Original language	English
Pages (from-to)	1909-1912
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	16
DOIs	https://doi.org/10.1016/S0040-4039(00)85995-X
State	Published - 15 Apr 1991
Externally published	Yes

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10.1016/S0040-4039(00)85995-X

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title = "Reductive and oxidative reactions of calix[4]arene derivatives",

abstract = "Reductive cleavage of 25,26,27,28-tetramethoxy-p-tert-butylcalix[4]arene with K results in the formation of 26,28-dimethoxy-p-t-butylcalix[4]arene. The reaction of 25,27-dihydroxycalix[4]arene with NO2BF4 in acetonitrile results in its oxidation to calixdiquinone 6.",

author = "Flavio Grynszpan and Nahum Dinoor and Biali, {Silvio E.}",

note = "Funding Information: This work was supported by the Bat-Sheva de Rothschild",

year = "1991",

month = apr,

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doi = "10.1016/S0040-4039(00)85995-X",

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AU - Grynszpan, Flavio

AU - Dinoor, Nahum

AU - Biali, Silvio E.

N1 - Funding Information: This work was supported by the Bat-Sheva de Rothschild

PY - 1991/4/15

Y1 - 1991/4/15

N2 - Reductive cleavage of 25,26,27,28-tetramethoxy-p-tert-butylcalix[4]arene with K results in the formation of 26,28-dimethoxy-p-t-butylcalix[4]arene. The reaction of 25,27-dihydroxycalix[4]arene with NO2BF4 in acetonitrile results in its oxidation to calixdiquinone 6.

AB - Reductive cleavage of 25,26,27,28-tetramethoxy-p-tert-butylcalix[4]arene with K results in the formation of 26,28-dimethoxy-p-t-butylcalix[4]arene. The reaction of 25,27-dihydroxycalix[4]arene with NO2BF4 in acetonitrile results in its oxidation to calixdiquinone 6.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Reductive and oxidative reactions of calix[4]arene derivatives

Abstract

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