Reactions of alkyl radicals with metal powders immersed in aqueous solutions

I. Rusonik; T. Zidky; H. Cohen; D. Meyerstein

doi:10.1007/s10720-005-0031-y

Reactions of alkyl radicals with metal powders immersed in aqueous solutions

I. Rusonik, T. Zidky, H. Cohen, D. Meyerstein

Department of Chemical Sciences

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3 Scopus citations

Abstract

The mechanism of dehalogenation was investigated in reactions between alkyl radicals and metal powders immersed in aqueous solutions. Radicals were obtained in the presence of an iron powder using radiochemical techniques. It was demonstrated that radicals enter into relatively fast reactions with metallic particles immersed in aqueous solutions and also in solutions of other solvents. It was stated that the variety of mechanisms responsible for the decomposition of the intermediate products formed could be significant in catalytic processes.

Original language	English
Pages (from-to)	115-118
Number of pages	4
Journal	Glass Physics and Chemistry
Volume	31
Issue number	1
DOIs	https://doi.org/10.1007/s10720-005-0031-y
State	Published - Jan 2005

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title = "Reactions of alkyl radicals with metal powders immersed in aqueous solutions",

abstract = "The mechanism of dehalogenation was investigated in reactions between alkyl radicals and metal powders immersed in aqueous solutions. Radicals were obtained in the presence of an iron powder using radiochemical techniques. It was demonstrated that radicals enter into relatively fast reactions with metallic particles immersed in aqueous solutions and also in solutions of other solvents. It was stated that the variety of mechanisms responsible for the decomposition of the intermediate products formed could be significant in catalytic processes.",

author = "I. Rusonik and T. Zidky and H. Cohen and D. Meyerstein",

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AU - Cohen, H.

AU - Meyerstein, D.

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AB - The mechanism of dehalogenation was investigated in reactions between alkyl radicals and metal powders immersed in aqueous solutions. Radicals were obtained in the presence of an iron powder using radiochemical techniques. It was demonstrated that radicals enter into relatively fast reactions with metallic particles immersed in aqueous solutions and also in solutions of other solvents. It was stated that the variety of mechanisms responsible for the decomposition of the intermediate products formed could be significant in catalytic processes.

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Reactions of alkyl radicals with metal powders immersed in aqueous solutions

Abstract

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