Radical reactions at surfaces

Tomer Zidki; Ronen Bar-Ziv; Ariela Burg; Yael Albo; Dan Meyerstein; L Leontiev; M. Zinigrad

Radical reactions at surfaces

Tomer Zidki, Ronen Bar-Ziv, Ariela Burg, Yael Albo, Dan Meyerstein, L Leontiev (Editor), M. Zinigrad (Editor)

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

This short review discusses recent mechanistic studies concerning the reactions of alkyl radicals with surfaces of metals and semiconductors suspended in aqueous solutions. The results point out that these reactions are fast and involve the formations of transients with -bonds between the radical and the surface. The mechanism of decomposition of the transients thus formed depends on the nature of the surface; the radical; the solvent etc. In reaction with nano-particles supported on semiconductors or on insulators the nature of the support affects dramatically the mechanism of decomposition of these transients. These processes have to be considered in catalytic, electro-chemical, photo-chemical and environmental processes.

Original language	English
Title of host publication	The optimization of composition, structure and properties of metals, oxides, composites, nano and amorphous materials
Pages	180-185
Number of pages	6
State	Published - 2016
Event	The Optimization of Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials: Seventh Israeli-Russian Bi-National Workshop 2008 - Perm, Russian Federation Duration: 4 Aug 2008 → 11 Aug 2008 Conference number: The Fifteenth Israeli - Russian Bi-National Workshop 2016

Conference

Conference	The Optimization of Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials
Country/Territory	Russian Federation
City	Perm
Period	4/08/08 → 11/08/08

Cite this

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title = "Radical reactions at surfaces",

abstract = "This short review discusses recent mechanistic studies concerning the reactions of alkyl radicals with surfaces of metals and semiconductors suspended in aqueous solutions. The results point out that these reactions are fast and involve the formations of transients with -bonds between the radical and the surface. The mechanism of decomposition of the transients thus formed depends on the nature of the surface; the radical; the solvent etc. In reaction with nano-particles supported on semiconductors or on insulators the nature of the support affects dramatically the mechanism of decomposition of these transients. These processes have to be considered in catalytic, electro-chemical, photo-chemical and environmental processes. ",

author = "Tomer Zidki and Ronen Bar-Ziv and Ariela Burg and Yael Albo and Dan Meyerstein and L Leontiev and M. Zinigrad",

year = "2016",

language = "אנגלית",

pages = "180--185",

booktitle = "The optimization of composition, structure and properties of metals, oxides, composites, nano and amorphous materials",

note = "The Optimization of Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials ; Conference date: 04-08-2008 Through 11-08-2008",

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Zidki, T, Bar-Ziv, R, Burg, A, Albo, Y , Meyerstein, D, Leontiev, L (ed.) & Zinigrad, M (ed.) 2016, Radical reactions at surfaces. in The optimization of composition, structure and properties of metals, oxides, composites, nano and amorphous materials. pp. 180-185, The Optimization of Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials, Perm, Russian Federation, 4/08/08.

TY - CHAP

T1 - Radical reactions at surfaces

AU - Zidki, Tomer

AU - Bar-Ziv, Ronen

AU - Burg, Ariela

AU - Albo, Yael

AU - Meyerstein, Dan

A2 - Leontiev, L

A2 - Zinigrad, M.

N1 - Conference code: The Fifteenth Israeli - Russian Bi-National Workshop 2016

PY - 2016

Y1 - 2016

N2 - This short review discusses recent mechanistic studies concerning the reactions of alkyl radicals with surfaces of metals and semiconductors suspended in aqueous solutions. The results point out that these reactions are fast and involve the formations of transients with -bonds between the radical and the surface. The mechanism of decomposition of the transients thus formed depends on the nature of the surface; the radical; the solvent etc. In reaction with nano-particles supported on semiconductors or on insulators the nature of the support affects dramatically the mechanism of decomposition of these transients. These processes have to be considered in catalytic, electro-chemical, photo-chemical and environmental processes.

AB - This short review discusses recent mechanistic studies concerning the reactions of alkyl radicals with surfaces of metals and semiconductors suspended in aqueous solutions. The results point out that these reactions are fast and involve the formations of transients with -bonds between the radical and the surface. The mechanism of decomposition of the transients thus formed depends on the nature of the surface; the radical; the solvent etc. In reaction with nano-particles supported on semiconductors or on insulators the nature of the support affects dramatically the mechanism of decomposition of these transients. These processes have to be considered in catalytic, electro-chemical, photo-chemical and environmental processes.

M3 - ???researchoutput.researchoutputtypes.contributiontobookanthology.chapter???

SP - 180

EP - 185

BT - The optimization of composition, structure and properties of metals, oxides, composites, nano and amorphous materials

T2 - The Optimization of Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials

Y2 - 4 August 2008 through 11 August 2008

ER -

Radical reactions at surfaces

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