TY - JOUR
T1 - Pyrophosphate as a stabilizer of Ni(III) ions in aqueous solutions
AU - Ittah, Elad
AU - Shamir, Dror
AU - Zilbermann, Israel
AU - Maimon, Eric
AU - Yardeni, Guy
AU - Shames, Alexander I.
AU - Meyerstein, Dan
N1 - Funding Information:
This project was financially supported by a joint grant of The Israel Atomic Energy Commission and The Israel Council of Higher Education .
PY - 2013
Y1 - 2013
N2 - Ni(II) ions in the presence of excess of pyrophosphate catalyze the decomposition of HSO5, while forming relatively stable Ni III(P2O7)n3 4n complexes. Excess pyrophosphate stabilizes the trivalent nickel species, NiIII(P2O7)n3 4naq, i.e. increases considerably its lifetime.
AB - Ni(II) ions in the presence of excess of pyrophosphate catalyze the decomposition of HSO5, while forming relatively stable Ni III(P2O7)n3 4n complexes. Excess pyrophosphate stabilizes the trivalent nickel species, NiIII(P2O7)n3 4naq, i.e. increases considerably its lifetime.
KW - Oxone
KW - Pyrophosphate
KW - Transition metal ions
UR - http://www.scopus.com/inward/record.url?scp=84885222251&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2013.05.002
DO - 10.1016/j.ica.2013.05.002
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AN - SCOPUS:84885222251
SN - 0020-1693
VL - 405
SP - 72
EP - 76
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -