Pulse radiolytic studies of the competition H + H and H + ferricyanide. The absolute rate constants

J. Rabani; D. Meyerstein

doi:10.1021/j100851a035

Pulse radiolytic studies of the competition H + H and H + ferricyanide. The absolute rate constants

J. Rabani, D. Meyerstein

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Abstract

The bimolecular rate constant of the reaction of hydrogen atoms with ferricyanide ions has been measured in aqueous solutions. We get k(H + Fe(CN)₆^3-) = (6.5 ± 0.5) × 10⁹ M^-1 sec^-1 in the region pH 2-3. Competition between H + Fe(CN)₆^3- and H + H yielded 2k(H + H) = (2.5 ± 0.4) × 10¹⁰ M^-1 sec^-1.

Original language	English
Pages (from-to)	1599-1603
Number of pages	5
Journal	Journal of Physical Chemistry
Volume	72
Issue number	5
DOIs	https://doi.org/10.1021/j100851a035
State	Published - 1968
Externally published	Yes

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title = "Pulse radiolytic studies of the competition H + H and H + ferricyanide. The absolute rate constants",

abstract = "The bimolecular rate constant of the reaction of hydrogen atoms with ferricyanide ions has been measured in aqueous solutions. We get k(H + Fe(CN)63-) = (6.5 ± 0.5) × 109 M-1 sec-1 in the region pH 2-3. Competition between H + Fe(CN)63- and H + H yielded 2k(H + H) = (2.5 ± 0.4) × 1010 M-1 sec-1.",

author = "J. Rabani and D. Meyerstein",

year = "1968",

doi = "10.1021/j100851a035",

language = "אנגלית",

volume = "72",

pages = "1599--1603",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - Pulse radiolytic studies of the competition H + H and H + ferricyanide. The absolute rate constants

AU - Rabani, J.

AU - Meyerstein, D.

PY - 1968

Y1 - 1968

N2 - The bimolecular rate constant of the reaction of hydrogen atoms with ferricyanide ions has been measured in aqueous solutions. We get k(H + Fe(CN)63-) = (6.5 ± 0.5) × 109 M-1 sec-1 in the region pH 2-3. Competition between H + Fe(CN)63- and H + H yielded 2k(H + H) = (2.5 ± 0.4) × 1010 M-1 sec-1.

AB - The bimolecular rate constant of the reaction of hydrogen atoms with ferricyanide ions has been measured in aqueous solutions. We get k(H + Fe(CN)63-) = (6.5 ± 0.5) × 109 M-1 sec-1 in the region pH 2-3. Competition between H + Fe(CN)63- and H + H yielded 2k(H + H) = (2.5 ± 0.4) × 1010 M-1 sec-1.

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DO - 10.1021/j100851a035

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AN - SCOPUS:33745862564

SN - 0022-3654

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SP - 1599

EP - 1603

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 5

ER -

Pulse radiolytic studies of the competition H + H and H + ferricyanide. The absolute rate constants

Abstract

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