Properties of (1,4,7,10,13-penta-azacyclohexadecane)nickel(III) in aqueous solutions: A pulse radiolytic study

Luigi Fabbrizzi, Hain Cohen, Dan Meyerstein

Research output: Contribution to journalArticlepeer-review

12 Scopus citations


The oxidation of (1,4,7,10,13-penta-azacyclohexadecane)nickel(II) by OH· radicals in aqueous solutions was studied, and the properties of the resulting nickel(III) complex are compared with those of analogous complexes [NiL]3+ where L is a tetra-azacyclotetradecane ligand. The difference in the properties is attributed to the fifth nitrogen donor atom which decreases the acidity of the central tervalent nickel.

Original languageEnglish
Pages (from-to)2125-2126
Number of pages2
JournalJournal of the Chemical Society. Dalton Transactions
Issue number9
StatePublished - 1983
Externally publishedYes


Dive into the research topics of 'Properties of (1,4,7,10,13-penta-azacyclohexadecane)nickel(III) in aqueous solutions: A pulse radiolytic study'. Together they form a unique fingerprint.

Cite this