Plausible mechanisms of the fenton-like reactions, M = Fe(II) and Co(II), in the presence of RCO2- substrates: Are OH• radicals formed in the process?

Haya Kornweitz; Ariela Burg; Dan Meyerstein

doi:10.1021/jp512826f

Plausible mechanisms of the fenton-like reactions, M = Fe(II) and Co(II), in the presence of RCO₂^- substrates: Are OH^• radicals formed in the process?

Haya Kornweitz, Ariela Burg, Dan Meyerstein

Department of Chemical Sciences

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34 Scopus citations

Abstract

DFT calculations concerning the plausible mechanism of Fenton-like reactions catalyzed by Fe(II) and Co(II) cations in the presence of carboxylate ligands suggest that hydroxyl radicals are not formed in these reactions. This conclusion suggests that the commonly accepted mechanisms of Fenton-like reactions induced oxidative stress and advanced oxidation processes have to be reconsidered.

Original language	English
Pages (from-to)	4200-4206
Number of pages	7
Journal	Journal of Physical Chemistry A
Volume	119
Issue number	18
DOIs	https://doi.org/10.1021/jp512826f
State	Published - 7 May 2015

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abstract = "DFT calculations concerning the plausible mechanism of Fenton-like reactions catalyzed by Fe(II) and Co(II) cations in the presence of carboxylate ligands suggest that hydroxyl radicals are not formed in these reactions. This conclusion suggests that the commonly accepted mechanisms of Fenton-like reactions induced oxidative stress and advanced oxidation processes have to be reconsidered.",

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AU - Meyerstein, Dan

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AB - DFT calculations concerning the plausible mechanism of Fenton-like reactions catalyzed by Fe(II) and Co(II) cations in the presence of carboxylate ligands suggest that hydroxyl radicals are not formed in these reactions. This conclusion suggests that the commonly accepted mechanisms of Fenton-like reactions induced oxidative stress and advanced oxidation processes have to be reconsidered.

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Plausible mechanisms of the fenton-like reactions, M = Fe(II) and Co(II), in the presence of RCO₂^- substrates: Are OH^• radicals formed in the process?

Abstract

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