TY - JOUR
T1 - Photocatalytic transformations of organic sulfur compounds and H 2S
AU - Vorontsov, A. V.
PY - 2008
Y1 - 2008
N2 - Modern views on the products, pathways and kinetic features of liquid- and gas-phase photocatalytic reactions of sulfur compounds in the presence of heterogeneous and homogeneous photocatalysts are generalised. Attention is focussed on the aliphatic and aromatic reduced sulfur compounds and pesticides. The reaction rate in the liquid and gas phases are analysed as function of solution pH, temperature, catalyst content, substrate concentration, solvent type, air moisture and added oxidants. Photocatalyst deactivation and the ways for recovery of its activity are considered.
AB - Modern views on the products, pathways and kinetic features of liquid- and gas-phase photocatalytic reactions of sulfur compounds in the presence of heterogeneous and homogeneous photocatalysts are generalised. Attention is focussed on the aliphatic and aromatic reduced sulfur compounds and pesticides. The reaction rate in the liquid and gas phases are analysed as function of solution pH, temperature, catalyst content, substrate concentration, solvent type, air moisture and added oxidants. Photocatalyst deactivation and the ways for recovery of its activity are considered.
UR - http://www.scopus.com/inward/record.url?scp=65249149094&partnerID=8YFLogxK
U2 - 10.1070/RC2008v077n10ABEH003805
DO - 10.1070/RC2008v077n10ABEH003805
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AN - SCOPUS:65249149094
SN - 0036-021X
VL - 77
SP - 909
EP - 926
JO - Russian Chemical Reviews
JF - Russian Chemical Reviews
IS - 10
ER -