Organocatalytic oxidative dimerization of alcohols to esters

Adi Abramovich; Hila Toledo; Evgeni Pisarevsky; Alex M. Szpilman

doi:10.1055/s-0032-1317018

Organocatalytic oxidative dimerization of alcohols to esters

Adi Abramovich, Hila Toledo, Evgeni Pisarevsky, Alex M. Szpilman

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.

Original language	English
Pages (from-to)	2261-2265
Number of pages	5
Journal	Synlett
Volume	23
Issue number	15
DOIs	https://doi.org/10.1055/s-0032-1317018
State	Published - 2012
Externally published	Yes

Keywords

alcohols
catalysis
dimerization
esters
oxidation

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10.1055/s-0032-1317018

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title = "Organocatalytic oxidative dimerization of alcohols to esters",

abstract = "2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.",

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AU - Abramovich, Adi

AU - Toledo, Hila

AU - Pisarevsky, Evgeni

AU - Szpilman, Alex M.

PY - 2012

Y1 - 2012

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AB - 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.

KW - alcohols

KW - catalysis

KW - dimerization

KW - esters

KW - oxidation

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VL - 23

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Organocatalytic oxidative dimerization of alcohols to esters

Abstract

Keywords

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