On the spectroelectrochemical characterization of the electrocatalytic oxidation of Cu(II) ethylenediamine

Dan Meyerstein; F. M. Hawkridge; Theodore Kuwana

doi:10.1016/S0022-0728(72)80382-6

On the spectroelectrochemical characterization of the electrocatalytic oxidation of Cu(II) ethylenediamine

Dan Meyerstein, F. M. Hawkridge, Theodore Kuwana

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Abstract

The electrolytic oxidation of the copper-ethylendiamine complex in alkaline solution has been studied using tin oxide optically transparent electrodes. During electrolysis, a thin solid deposit assumed to contain divalent copper oxide or hydroxide, formed on the electrode surface. This deposit appeared to facilitate the electrocatalytic oxidation of CuEn₂²⁺ and OH^- ions. Spectroscopic and electrochemical data obtained during various electrochemical experiments suggested a mechanism involving trivalent copper as an intermediate in the catalytic step.

Original language	English
Pages (from-to)	377-384
Number of pages	8
Journal	Journal of Electroanalytical Chemistry
Volume	40
Issue number	2
DOIs	https://doi.org/10.1016/S0022-0728(72)80382-6
State	Published - Dec 1972
Externally published	Yes

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10.1016/S0022-0728(72)80382-6

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title = "On the spectroelectrochemical characterization of the electrocatalytic oxidation of Cu(II) ethylenediamine",

abstract = "The electrolytic oxidation of the copper-ethylendiamine complex in alkaline solution has been studied using tin oxide optically transparent electrodes. During electrolysis, a thin solid deposit assumed to contain divalent copper oxide or hydroxide, formed on the electrode surface. This deposit appeared to facilitate the electrocatalytic oxidation of CuEn22+ and OH- ions. Spectroscopic and electrochemical data obtained during various electrochemical experiments suggested a mechanism involving trivalent copper as an intermediate in the catalytic step.",

author = "Dan Meyerstein and Hawkridge, \{F. M.\} and Theodore Kuwana",

year = "1972",

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AU - Meyerstein, Dan

AU - Hawkridge, F. M.

AU - Kuwana, Theodore

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Y1 - 1972/12

N2 - The electrolytic oxidation of the copper-ethylendiamine complex in alkaline solution has been studied using tin oxide optically transparent electrodes. During electrolysis, a thin solid deposit assumed to contain divalent copper oxide or hydroxide, formed on the electrode surface. This deposit appeared to facilitate the electrocatalytic oxidation of CuEn22+ and OH- ions. Spectroscopic and electrochemical data obtained during various electrochemical experiments suggested a mechanism involving trivalent copper as an intermediate in the catalytic step.

AB - The electrolytic oxidation of the copper-ethylendiamine complex in alkaline solution has been studied using tin oxide optically transparent electrodes. During electrolysis, a thin solid deposit assumed to contain divalent copper oxide or hydroxide, formed on the electrode surface. This deposit appeared to facilitate the electrocatalytic oxidation of CuEn22+ and OH- ions. Spectroscopic and electrochemical data obtained during various electrochemical experiments suggested a mechanism involving trivalent copper as an intermediate in the catalytic step.

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AN - SCOPUS:3543074587

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JO - Journal of Electroanalytical Chemistry

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ER -

On the spectroelectrochemical characterization of the electrocatalytic oxidation of Cu(II) ethylenediamine

Abstract

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