Modifying the sorption capacity of biopolymers by the mechanochemical activation

Svetlana Lugovskoy; Michael Zinigrad; Moshe Eliaszade

doi:10.4028/www.scientific.net/DDF.326-328.504

Modifying the sorption capacity of biopolymers by the mechanochemical activation

Svetlana Lugovskoy, Michael Zinigrad, Moshe Eliaszade

Department of Chemical Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Mechanochemical activation (MCA) of electrode lignin was performed and the activated lignin was studied by IR-spectroscopy for different activation times. The activated lignin was tested for the ability of binding Cr₂O ₇ ^2-, Cu²⁺, Ni²⁺ ions. It was established that structure deformation, which does not distort the stronger hydrogen bond lattice, but leads to the formation of highly developed surface with active functional groups, occurs in the course of MCA. Weaker inter-layer bonds are broken in the activation process and quickly recovered after the load release. The comparison of the sorption capacity of Cr₂O ₇ ^2-, Cu²⁺, Ni²⁺ ions by the MCA treated vs. inactivated lignin for different activation times was performed.

Original language	English
Title of host publication	Diffusion in Solids and Liquids VII
Subtitle of host publication	Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure and Properties - Nanodiffusion and Nanostructured Materials
Pages	504-508
Number of pages	5
Volume	326-328
DOIs	https://doi.org/10.4028/www.scientific.net/DDF.326-328.504
State	Published - 2012
Event	7th International Conference on Diffusion in Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure and Properties - Nanodiffusion and Nanostructured Materials, DSL 2011 - Algarve, Portugal Duration: 26 Jun 2011 → 30 Jun 2011

Conference

Conference	7th International Conference on Diffusion in Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure and Properties - Nanodiffusion and Nanostructured Materials, DSL 2011
Country/Territory	Portugal
City	Algarve
Period	26/06/11 → 30/06/11

Keywords

IR-spectroscopy
Lignin activation
Mechanochemical activation

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10.4028/www.scientific.net/DDF.326-328.504

Cite this

Lugovskoy, S., Zinigrad, M., & Eliaszade, M. (2012). Modifying the sorption capacity of biopolymers by the mechanochemical activation. In Diffusion in Solids and Liquids VII: Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure and Properties - Nanodiffusion and Nanostructured Materials (Vol. 326-328, pp. 504-508) https://doi.org/10.4028/www.scientific.net/DDF.326-328.504

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abstract = "Mechanochemical activation (MCA) of electrode lignin was performed and the activated lignin was studied by IR-spectroscopy for different activation times. The activated lignin was tested for the ability of binding Cr2O 7 2-, Cu2+, Ni2+ ions. It was established that structure deformation, which does not distort the stronger hydrogen bond lattice, but leads to the formation of highly developed surface with active functional groups, occurs in the course of MCA. Weaker inter-layer bonds are broken in the activation process and quickly recovered after the load release. The comparison of the sorption capacity of Cr2O 7 2-, Cu2+, Ni2+ ions by the MCA treated vs. inactivated lignin for different activation times was performed.",

keywords = "IR-spectroscopy, Lignin activation, Mechanochemical activation",

author = "Svetlana Lugovskoy and Michael Zinigrad and Moshe Eliaszade",

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booktitle = "Diffusion in Solids and Liquids VII",

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Lugovskoy, S , Zinigrad, M & Eliaszade, M 2012, Modifying the sorption capacity of biopolymers by the mechanochemical activation. in Diffusion in Solids and Liquids VII: Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure and Properties - Nanodiffusion and Nanostructured Materials. vol. 326-328, pp. 504-508, 7th International Conference on Diffusion in Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure and Properties - Nanodiffusion and Nanostructured Materials, DSL 2011, Algarve, Portugal, 26/06/11. https://doi.org/10.4028/www.scientific.net/DDF.326-328.504

Modifying the sorption capacity of biopolymers by the mechanochemical activation. / Lugovskoy, Svetlana ; Zinigrad, Michael; Eliaszade, Moshe.
Diffusion in Solids and Liquids VII: Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure and Properties - Nanodiffusion and Nanostructured Materials. Vol. 326-328 2012. p. 504-508.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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KW - IR-spectroscopy

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KW - Mechanochemical activation

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Modifying the sorption capacity of biopolymers by the mechanochemical activation

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