Modelling of electrification in steady state and transient regimes

D. A. Bograchev, S. Martemianov, T. Paillat

Research output: Contribution to journalArticlepeer-review

2 Scopus citations


A microscopic model of electrification phenomena in steady state and transient regimes has been developed. The model has been applied for analysis of experimental data failing to be explained in the frame of classical macroscopic approach. Various boundary conditions have been studied regarding the possibility of experiential data fitting. The hybrid boundary condition has been suggested for explaining steady state and transient experiments. The proposed boundary condition can be related to the coexistence of two reactions on the active surface. The first reaction runs under the diffusion control (fast reaction) and the second one is limited by the kinetics (slow reaction).

Original languageEnglish
Pages (from-to)517-523
Number of pages7
JournalJournal of Electrostatics
Issue number6
StatePublished - Dec 2012
Externally publishedYes


  • Double layer
  • Electrification
  • Streaming current


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