Measurements and modeling of the VLE properties of n-hexadecane in supercritical binary propane+n-butane solvent

Vener F. Khairutdinov; Farid M. Gumerov; Ilnar Sh Khabriev; Mansur I. Farakhov; Ilfat Z. Salikhov; Ilya Polishuk; Ilmutdin M. Abdulagatov

doi:10.1016/j.fluid.2020.112502

Measurements and modeling of the VLE properties of n-hexadecane in supercritical binary propane+n-butane solvent

Vener F. Khairutdinov
, Farid M. Gumerov
, Ilnar Sh Khabriev
, Mansur I. Farakhov
, Ilfat Z. Salikhov
, Ilya Polishuk
, Ilmutdin M. Abdulagatov

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

This study reports the new VLE data of n-hexadecane in pure propane at 403 Kand in the supercritical solvent mixture (0.527 propane+0.473 n-butane mole fraction) at 403 K, 423 K, and 443 K over the pressure range from (1.22–6.31) MPa. The measurements were made using a high-temperature and high-pressure optical cell.The combined expanded uncertainty of the temperature, pressure, and concentration measurements at 95% confidence level with a coverage factor of k = 2 is estimated at 0.15 K, 0.05%, and 3%, respectively. The measured VLE data for binary propane + hexadecane and ternary propane + n-butane + n-hexadecane mixtures were used to examine the predictive capabilities PC-SAFT and PR EoS.

Original language	English
Article number	112502
Journal	Fluid Phase Equilibria
Volume	510
DOIs	https://doi.org/10.1016/j.fluid.2020.112502
State	Published - 15 Apr 2020

Keywords

Critical curve
Critical point
Equation of state
Phase diagram
Supercritical solvent
VLE measurements
n-hexadecane+propane mixture
n-hexadecane+propane+n-butane mixture

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10.1016/j.fluid.2020.112502

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@article{012488ee879c4892bae3821c18db04f7,

title = "Measurements and modeling of the VLE properties of n-hexadecane in supercritical binary propane+n-butane solvent",

abstract = "This study reports the new VLE data of n-hexadecane in pure propane at 403 Kand in the supercritical solvent mixture (0.527 propane+0.473 n-butane mole fraction) at 403 K, 423 K, and 443 K over the pressure range from (1.22{\textendash}6.31) MPa. The measurements were made using a high-temperature and high-pressure optical cell.The combined expanded uncertainty of the temperature, pressure, and concentration measurements at 95\% confidence level with a coverage factor of k = 2 is estimated at 0.15 K, 0.05\%, and 3\%, respectively. The measured VLE data for binary propane + hexadecane and ternary propane + n-butane + n-hexadecane mixtures were used to examine the predictive capabilities PC-SAFT and PR EoS.",

keywords = "Critical curve, Critical point, Equation of state, Phase diagram, Supercritical solvent, VLE measurements, n-hexadecane+propane mixture, n-hexadecane+propane+n-butane mixture",

author = "Khairutdinov, \{Vener F.\} and Gumerov, \{Farid M.\} and Khabriev, \{Ilnar Sh\} and Farakhov, \{Mansur I.\} and Salikhov, \{Ilfat Z.\} and Ilya Polishuk and Abdulagatov, \{Ilmutdin M.\}",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = apr,

day = "15",

doi = "10.1016/j.fluid.2020.112502",

language = "אנגלית",

volume = "510",

journal = "Fluid Phase Equilibria",

issn = "0378-3812",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Measurements and modeling of the VLE properties of n-hexadecane in supercritical binary propane+n-butane solvent

AU - Khairutdinov, Vener F.

AU - Gumerov, Farid M.

AU - Khabriev, Ilnar Sh

AU - Farakhov, Mansur I.

AU - Salikhov, Ilfat Z.

AU - Polishuk, Ilya

AU - Abdulagatov, Ilmutdin M.

PY - 2020/4/15

Y1 - 2020/4/15

N2 - This study reports the new VLE data of n-hexadecane in pure propane at 403 Kand in the supercritical solvent mixture (0.527 propane+0.473 n-butane mole fraction) at 403 K, 423 K, and 443 K over the pressure range from (1.22–6.31) MPa. The measurements were made using a high-temperature and high-pressure optical cell.The combined expanded uncertainty of the temperature, pressure, and concentration measurements at 95% confidence level with a coverage factor of k = 2 is estimated at 0.15 K, 0.05%, and 3%, respectively. The measured VLE data for binary propane + hexadecane and ternary propane + n-butane + n-hexadecane mixtures were used to examine the predictive capabilities PC-SAFT and PR EoS.

AB - This study reports the new VLE data of n-hexadecane in pure propane at 403 Kand in the supercritical solvent mixture (0.527 propane+0.473 n-butane mole fraction) at 403 K, 423 K, and 443 K over the pressure range from (1.22–6.31) MPa. The measurements were made using a high-temperature and high-pressure optical cell.The combined expanded uncertainty of the temperature, pressure, and concentration measurements at 95% confidence level with a coverage factor of k = 2 is estimated at 0.15 K, 0.05%, and 3%, respectively. The measured VLE data for binary propane + hexadecane and ternary propane + n-butane + n-hexadecane mixtures were used to examine the predictive capabilities PC-SAFT and PR EoS.

KW - Critical curve

KW - Critical point

KW - Equation of state

KW - Phase diagram

KW - Supercritical solvent

KW - VLE measurements

KW - n-hexadecane+propane mixture

KW - n-hexadecane+propane+n-butane mixture

UR - https://www.scopus.com/pages/publications/85078890615

U2 - 10.1016/j.fluid.2020.112502

DO - 10.1016/j.fluid.2020.112502

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AN - SCOPUS:85078890615

SN - 0378-3812

VL - 510

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

M1 - 112502

ER -

Measurements and modeling of the VLE properties of n-hexadecane in supercritical binary propane+n-butane solvent

Abstract

Keywords

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