Luminescence and absorption spectra of Eu-complex-doped PVDF film: Influence of controlled stretch

Roman Pogreb; Gene Whyman; Mikhail Mestechkin; Shmuel Sternklar; Albina Musin; Yelena Bormashenko; Mordechai Hakham-Itzhaq; Michael Tseitlin; Oleg Popov; Vlad Lirtsman; Dan Davidov; Edward Bormashenko

doi:10.1117/12.643743

Luminescence and absorption spectra of Eu-complex-doped PVDF film: Influence of controlled stretch

Roman Pogreb, Gene Whyman, Mikhail Mestechkin, Shmuel Sternklar, Albina Musin, Yelena Bormashenko, Mordechai Hakham-Itzhaq, Michael Tseitlin, Oleg Popov, Vlad Lirtsman, Dan Davidov, Edward Bormashenko

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Scopus citations

Abstract

Poly(vinylidenefluoride) film (PVDF) doped with Eu(III)(NO ₃)₃(o-Phenanthroline)₂ complex (complex A) was manufactured using an extrusion technique. Emission spectrum of the film was compared to spectra of the dopant and polyethylene based film. Stretching the film resulted in a sharp growth of intensity and reshaping of the luminescence spectrum. The impact of the PVDF matrix on the photoluminescence spectra of complex A is attributed to the Stark effect. Reasons for the increase of luminescence intensity are discussed. Quantum chemical calculations revealed a marked longwave shift of the lowest triplet and singlet energy levels of complex A compared to free phenanthroline. The amplification and frequency shifting of the luminescent spectrum of europium-complex-doped PVDF may lead to promising applications.

Original language	English
Title of host publication	Proceedings of SPIE - The International Society for Optical Engineering
DOIs	https://doi.org/10.1117/12.643743
State	Published - 2006
Event	Optical Components and Materials III - San Jose, CA, United States Duration: 23 Jan 2006 → 25 Jan 2006

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	6116
ISSN (Print)	0277-786X

Conference

Conference	Optical Components and Materials III
Country/Territory	United States
City	San Jose, CA
Period	23/01/06 → 25/01/06

Keywords

Eu(III) organic complexes
Luminescence
Piezoelectricity
Polymers

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10.1117/12.643743

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Pogreb, R., Whyman, G., Mestechkin, M., Sternklar, S., Musin, A., Bormashenko, Y., Hakham-Itzhaq, M., Tseitlin, M., Popov, O., Lirtsman, V., Davidov, D., & Bormashenko, E. (2006). Luminescence and absorption spectra of Eu-complex-doped PVDF film: Influence of controlled stretch. In Proceedings of SPIE - The International Society for Optical Engineering Article 61160E (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 6116). https://doi.org/10.1117/12.643743

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title = "Luminescence and absorption spectra of Eu-complex-doped PVDF film: Influence of controlled stretch",

abstract = "Poly(vinylidenefluoride) film (PVDF) doped with Eu(III)(NO 3)3(o-Phenanthroline)2 complex (complex A) was manufactured using an extrusion technique. Emission spectrum of the film was compared to spectra of the dopant and polyethylene based film. Stretching the film resulted in a sharp growth of intensity and reshaping of the luminescence spectrum. The impact of the PVDF matrix on the photoluminescence spectra of complex A is attributed to the Stark effect. Reasons for the increase of luminescence intensity are discussed. Quantum chemical calculations revealed a marked longwave shift of the lowest triplet and singlet energy levels of complex A compared to free phenanthroline. The amplification and frequency shifting of the luminescent spectrum of europium-complex-doped PVDF may lead to promising applications.",

keywords = "Eu(III) organic complexes, Luminescence, Piezoelectricity, Polymers",

author = "Roman Pogreb and Gene Whyman and Mikhail Mestechkin and Shmuel Sternklar and Albina Musin and Yelena Bormashenko and Mordechai Hakham-Itzhaq and Michael Tseitlin and Oleg Popov and Vlad Lirtsman and Dan Davidov and Edward Bormashenko",

year = "2006",

doi = "10.1117/12.643743",

language = "אנגלית",

isbn = "081946158X",

series = "Proceedings of SPIE - The International Society for Optical Engineering",

booktitle = "Proceedings of SPIE - The International Society for Optical Engineering",

note = "Optical Components and Materials III ; Conference date: 23-01-2006 Through 25-01-2006",

}

Pogreb, R , Whyman, G, Mestechkin, M, Sternklar, S , Musin, A, Bormashenko, Y, Hakham-Itzhaq, M, Tseitlin, M, Popov, O, Lirtsman, V, Davidov, D & Bormashenko, E 2006, Luminescence and absorption spectra of Eu-complex-doped PVDF film: Influence of controlled stretch. in Proceedings of SPIE - The International Society for Optical Engineering., 61160E, Proceedings of SPIE - The International Society for Optical Engineering, vol. 6116, Optical Components and Materials III, San Jose, CA, United States, 23/01/06. https://doi.org/10.1117/12.643743

Luminescence and absorption spectra of Eu-complex-doped PVDF film: Influence of controlled stretch. / Pogreb, Roman ; Whyman, Gene; Mestechkin, Mikhail et al.
Proceedings of SPIE - The International Society for Optical Engineering. 2006. 61160E (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 6116).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Whyman, Gene

AU - Mestechkin, Mikhail

AU - Sternklar, Shmuel

AU - Musin, Albina

AU - Bormashenko, Yelena

AU - Hakham-Itzhaq, Mordechai

AU - Tseitlin, Michael

AU - Popov, Oleg

AU - Lirtsman, Vlad

AU - Davidov, Dan

AU - Bormashenko, Edward

PY - 2006

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N2 - Poly(vinylidenefluoride) film (PVDF) doped with Eu(III)(NO 3)3(o-Phenanthroline)2 complex (complex A) was manufactured using an extrusion technique. Emission spectrum of the film was compared to spectra of the dopant and polyethylene based film. Stretching the film resulted in a sharp growth of intensity and reshaping of the luminescence spectrum. The impact of the PVDF matrix on the photoluminescence spectra of complex A is attributed to the Stark effect. Reasons for the increase of luminescence intensity are discussed. Quantum chemical calculations revealed a marked longwave shift of the lowest triplet and singlet energy levels of complex A compared to free phenanthroline. The amplification and frequency shifting of the luminescent spectrum of europium-complex-doped PVDF may lead to promising applications.

AB - Poly(vinylidenefluoride) film (PVDF) doped with Eu(III)(NO 3)3(o-Phenanthroline)2 complex (complex A) was manufactured using an extrusion technique. Emission spectrum of the film was compared to spectra of the dopant and polyethylene based film. Stretching the film resulted in a sharp growth of intensity and reshaping of the luminescence spectrum. The impact of the PVDF matrix on the photoluminescence spectra of complex A is attributed to the Stark effect. Reasons for the increase of luminescence intensity are discussed. Quantum chemical calculations revealed a marked longwave shift of the lowest triplet and singlet energy levels of complex A compared to free phenanthroline. The amplification and frequency shifting of the luminescent spectrum of europium-complex-doped PVDF may lead to promising applications.

KW - Eu(III) organic complexes

KW - Luminescence

KW - Piezoelectricity

KW - Polymers

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BT - Proceedings of SPIE - The International Society for Optical Engineering

Y2 - 23 January 2006 through 25 January 2006

ER -

Luminescence and absorption spectra of Eu-complex-doped PVDF film: Influence of controlled stretch

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