Limiting current in iodine-iodide system on vertical electrode under conditions of natural convection

L. A. Reznikova; E. E. Morgunova; D. A. Bograchev; A. P. Grigin; A. D. Davydov

doi:10.1023/a:1016626006594

Limiting current in iodine-iodide system on vertical electrode under conditions of natural convection

L. A. Reznikova, E. E. Morgunova, D. A. Bograchev, A. P. Grigin, A. D. Davydov

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2 Scopus citations

Abstract

The limiting current of the triiodide reduction on a vertical plane electrode in solutions containing excess potassium iodide is calculated by the Karman method for natural-convection conditions. Equations for the average and local limiting currents (which depend on the electrode height), the boundary layer thickness, and the vertical component of the fluid velocity are derived. The average limiting currents, experimentally determined as functions of concentrations of solution components and electrode's height, are compared to calculated values.

Original language	English
Pages (from-to)	382-387
Number of pages	6
Journal	Russian Journal of Electrochemistry
Volume	37
Issue number	4
DOIs	https://doi.org/10.1023/a:1016626006594
State	Published - 2001
Externally published	Yes

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abstract = "The limiting current of the triiodide reduction on a vertical plane electrode in solutions containing excess potassium iodide is calculated by the Karman method for natural-convection conditions. Equations for the average and local limiting currents (which depend on the electrode height), the boundary layer thickness, and the vertical component of the fluid velocity are derived. The average limiting currents, experimentally determined as functions of concentrations of solution components and electrode's height, are compared to calculated values.",

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AU - Grigin, A. P.

AU - Davydov, A. D.

PY - 2001

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AB - The limiting current of the triiodide reduction on a vertical plane electrode in solutions containing excess potassium iodide is calculated by the Karman method for natural-convection conditions. Equations for the average and local limiting currents (which depend on the electrode height), the boundary layer thickness, and the vertical component of the fluid velocity are derived. The average limiting currents, experimentally determined as functions of concentrations of solution components and electrode's height, are compared to calculated values.

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Limiting current in iodine-iodide system on vertical electrode under conditions of natural convection

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