Kinetics of β-hydroxyl elimination from [(H2O)mCuIICH2C(CH3) 2OH]+ in aqueous solution. A pulse-radiolysis study

Haim Cohen; Dan Meyerstein

doi:10.1039/F19888404157

Kinetics of β-hydroxyl elimination from [(H₂O)_mCu^IICH₂C(CH₃) ₂OH]⁺ in aqueous solution. A pulse-radiolysis study

Haim Cohen, Dan Meyerstein

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Abstract

The reaction of ^.CH₂C(CH₃)₂OH with Cu_aq⁺ yields the short-lived transient complex [Cu^IICH₂C(CH₃)₂OH]_aq ⁺. The spectrum of the latter complex is reported. [Cu^IICH₂C(CH₃)₂OH]_aq ⁺ decomposes into Cu_aq⁺ + CH₂=C(CH₃)₂+OH^-. The specific rate of this reaction is 5.0 × 10⁴ + 8.6 × 10⁷[H₃O⁺] s^-1. The kinetics are discussed in comparison with those of analogous reactions reported earlier.

Original language	English
Pages (from-to)	4157-4160
Number of pages	4
Journal	Physical Chemistry Chemical Physics
Volume	84
Issue number	11
DOIs	https://doi.org/10.1039/F19888404157
State	Published - 1988
Externally published	Yes

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title = "Kinetics of β-hydroxyl elimination from [(H2O)mCuIICH2C(CH3) 2OH]+ in aqueous solution. A pulse-radiolysis study",

abstract = "The reaction of .CH2C(CH3)2OH with Cuaq+ yields the short-lived transient complex [CuIICH2C(CH3)2OH]aq +. The spectrum of the latter complex is reported. [CuIICH2C(CH3)2OH]aq + decomposes into Cuaq+ + CH2=C(CH3)2+OH-. The specific rate of this reaction is 5.0 × 104 + 8.6 × 107[H3O+] s-1. The kinetics are discussed in comparison with those of analogous reactions reported earlier.",

author = "Haim Cohen and Dan Meyerstein",

year = "1988",

doi = "10.1039/F19888404157",

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publisher = "Royal Society of Chemistry",

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T1 - Kinetics of β-hydroxyl elimination from [(H2O)mCuIICH2C(CH3) 2OH]+ in aqueous solution. A pulse-radiolysis study

AU - Cohen, Haim

AU - Meyerstein, Dan

PY - 1988

Y1 - 1988

N2 - The reaction of .CH2C(CH3)2OH with Cuaq+ yields the short-lived transient complex [CuIICH2C(CH3)2OH]aq +. The spectrum of the latter complex is reported. [CuIICH2C(CH3)2OH]aq + decomposes into Cuaq+ + CH2=C(CH3)2+OH-. The specific rate of this reaction is 5.0 × 104 + 8.6 × 107[H3O+] s-1. The kinetics are discussed in comparison with those of analogous reactions reported earlier.

AB - The reaction of .CH2C(CH3)2OH with Cuaq+ yields the short-lived transient complex [CuIICH2C(CH3)2OH]aq +. The spectrum of the latter complex is reported. [CuIICH2C(CH3)2OH]aq + decomposes into Cuaq+ + CH2=C(CH3)2+OH-. The specific rate of this reaction is 5.0 × 104 + 8.6 × 107[H3O+] s-1. The kinetics are discussed in comparison with those of analogous reactions reported earlier.

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U2 - 10.1039/F19888404157

DO - 10.1039/F19888404157

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SN - 0300-9599

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JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 11

ER -

Kinetics of β-hydroxyl elimination from [(H₂O)_mCu^IICH₂C(CH₃) ₂OH]⁺ in aqueous solution. A pulse-radiolysis study

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