TY - JOUR
T1 - Intramolecular Electron Transfer of Coordinated Pyrazinecarboxylato Radicals to Cobalt(III)
T2 - A Pulse Radiolytic Study
AU - Wieghardt, Karl
AU - Cohen, Haim
AU - Meyerstein, Dan
PY - 1978/8
Y1 - 1978/8
N2 - Short‐lived radical intermediates of electron‐transfer reactions have only been postulated so far. An example is species 2, assumed to occur in the reduction of the complex 1 by CrII. The first preparation and characterization of such radicals by pulse radiolysis has now been accomplished. \documentclass{article}\usepackage{amssymb}\pagestyle{empty}\begin{document}$({\rm CH}_3)_2\mathop {\rm C}\limits^{\bullet}\raise1pt\hbox{---}{\rm OH}$\end{document} (from solvent isopropanol) served as electron‐transfer agent. (Figure Presented.)
AB - Short‐lived radical intermediates of electron‐transfer reactions have only been postulated so far. An example is species 2, assumed to occur in the reduction of the complex 1 by CrII. The first preparation and characterization of such radicals by pulse radiolysis has now been accomplished. \documentclass{article}\usepackage{amssymb}\pagestyle{empty}\begin{document}$({\rm CH}_3)_2\mathop {\rm C}\limits^{\bullet}\raise1pt\hbox{---}{\rm OH}$\end{document} (from solvent isopropanol) served as electron‐transfer agent. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985630822&partnerID=8YFLogxK
U2 - 10.1002/anie.197806081
DO - 10.1002/anie.197806081
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AN - SCOPUS:84985630822
SN - 0570-0833
VL - 17
SP - 608
EP - 609
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 8
ER -