Imidazolium-Based Energetic Materials

Sagi Sevilia, Galit Parvari, Jonathan Bernstein, Natalia Fridman, Dan Grinstein, Levi Gottlieb, Yoav Eichen, Alex M. Szpilman

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

We show that 1-(2-hydroxyethyl)-1H-imidazol-3-ium and 1-(2-hydroxyethyl)-3-methyl-1H-imidazol-3-ium salts, as well as the salts of their nitrite esters, that include oxidizing anions (so-called explosphores) such as nitrate, picrate and perchlorate„ are endowed with high enthalpies of decomposition, high decomposition temperatures, and high densities. This combined with detonation velocities and pressures calculated using Explo5, indicates that especially the perchlorate salts have potential as energetic materials. All the studied salts are easily preparable in up to gram scale through two or three synthetic steps from simple imidazole. Many of these salts are ionic liquids, which may render them useful as energetic plasticizers or gel filled materials.

Original languageEnglish
Article numbere202200322
JournalChemistrySelect
Volume7
Issue number14
DOIs
StatePublished - 12 Apr 2022

Keywords

  • Energetic Materials
  • Explosophores
  • Imidazolium Salts
  • Ionic Liquids

Fingerprint

Dive into the research topics of 'Imidazolium-Based Energetic Materials'. Together they form a unique fingerprint.

Cite this