Heterogeneous oxidation of ethanol over Cu(OH)2/α-Fe2O3 under visible light

Ekaterina V. Kuznetsova; Evgueni N. Savinov; Alexandre V. Vorontsov; Panagiotis Smirniotis

doi:10.1023/A:1022694129528

Heterogeneous oxidation of ethanol over Cu(OH)₂/α-Fe₂O₃ under visible light

Ekaterina V. Kuznetsova
, Evgueni N. Savinov
, Alexandre V. Vorontsov
, Panagiotis Smirniotis

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A Cu(OH)₂/α-Fe₂O₃ photocatalyst is shown to be active in the gas phase oxidation of ethanol under visible light. The calculated initial quantum efficiency of the ethanol photooxidation is 0.1-1%. However, ethanol is oxidized only into acetic acid, which deactivates the catalyst.

Original language	English
Pages (from-to)	341-348
Number of pages	8
Journal	Reaction Kinetics and Catalysis Letters
Volume	78
Issue number	2
DOIs	https://doi.org/10.1023/A:1022694129528
State	Published - 2003
Externally published	Yes

Keywords

Copper hydroxides
Multielectron reactions
Organic oxidation
Photocatalysis

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10.1023/A:1022694129528

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@article{e2e6513855fc4d47a64111cc89cdeb40,

title = "Heterogeneous oxidation of ethanol over Cu(OH)2/α-Fe2O3 under visible light",

abstract = "A Cu(OH)2/α-Fe2O3 photocatalyst is shown to be active in the gas phase oxidation of ethanol under visible light. The calculated initial quantum efficiency of the ethanol photooxidation is 0.1-1\%. However, ethanol is oxidized only into acetic acid, which deactivates the catalyst.",

keywords = "Copper hydroxides, Multielectron reactions, Organic oxidation, Photocatalysis",

author = "Kuznetsova, \{Ekaterina V.\} and Savinov, \{Evgueni N.\} and Vorontsov, \{Alexandre V.\} and Panagiotis Smirniotis",

note = "Funding Information: Acknowledgment. We gratefully acknowledge financial support of the NATO Science for Peace Program (Project Reference Number: sfp 974209) and of the Russian Foundation of Basic Research (Project “Scientific schools” \# 00-15-97446). We are also grateful to Drs. G.L. Elizarova and I.L. Kraevskaya for the assistance provided.",

year = "2003",

doi = "10.1023/A:1022694129528",

language = "אנגלית",

volume = "78",

pages = "341--348",

number = "2",

}

TY - JOUR

T1 - Heterogeneous oxidation of ethanol over Cu(OH)2/α-Fe2O3 under visible light

AU - Kuznetsova, Ekaterina V.

AU - Savinov, Evgueni N.

AU - Vorontsov, Alexandre V.

AU - Smirniotis, Panagiotis

N1 - Funding Information: Acknowledgment. We gratefully acknowledge financial support of the NATO Science for Peace Program (Project Reference Number: sfp 974209) and of the Russian Foundation of Basic Research (Project “Scientific schools” # 00-15-97446). We are also grateful to Drs. G.L. Elizarova and I.L. Kraevskaya for the assistance provided.

PY - 2003

Y1 - 2003

N2 - A Cu(OH)2/α-Fe2O3 photocatalyst is shown to be active in the gas phase oxidation of ethanol under visible light. The calculated initial quantum efficiency of the ethanol photooxidation is 0.1-1%. However, ethanol is oxidized only into acetic acid, which deactivates the catalyst.

AB - A Cu(OH)2/α-Fe2O3 photocatalyst is shown to be active in the gas phase oxidation of ethanol under visible light. The calculated initial quantum efficiency of the ethanol photooxidation is 0.1-1%. However, ethanol is oxidized only into acetic acid, which deactivates the catalyst.

KW - Copper hydroxides

KW - Multielectron reactions

KW - Organic oxidation

KW - Photocatalysis

UR - https://www.scopus.com/pages/publications/0037252838

U2 - 10.1023/A:1022694129528

DO - 10.1023/A:1022694129528

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AN - SCOPUS:0037252838

SN - 0133-1736

VL - 78

SP - 341

EP - 348

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 2

ER -

Heterogeneous oxidation of ethanol over Cu(OH)₂/α-Fe₂O₃ under visible light

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