Exclusive C-C oxidative addition in a rhodium thiophosphoryl pincer complex and computational evidence for an ν ³-C-C-H agostic intermediate

Keyphrases

• Repulsion 100%
• Oxidative Addition 100%
• Agostic 100%
• Rhodium 100%
• Pincer Complexes 100%
• C-H Cleavage 100%
• Methyl 50%
• Acetone 50%
• Thermodynamics 50%
• Cyclooctatetraene 50%
• Reaction Pathway 50%
• C-H Bond 50%
• Electron Density 50%
• Lone Electron Pair 50%
• C-C Bond 50%
• Sulfur Atom 50%
• D-orbital 50%
• Pincer Ligands 50%
• DFT Study 50%
• Electronegativity 50%
• Room Temperature Reaction 50%
• Agostic Interactions 50%
• Cleavage Pathway 50%
• Rh(I) 50%
• Hydride Ligands 50%

Chemistry

• Rhodium 100%
• Oxidative Addition 100%
• Pincer Complex 100%
• Chemistry 50%
• Density Functional Theory 50%
• Ambient Reaction Temperature 50%
• Sulfur Atom 50%
• BF 4 50%
• Electron Density 50%
• Electronegativity 50%
• Lone-Pair Electron 50%