Electronic structure of 9-mesityl-10-methylacridinium in ground and excited states: Charge-shift mechanism introduced by counter anion shift

Shmuel Zilberg

doi:10.1039/c0cp00491j

Electronic structure of 9-mesityl-10-methylacridinium in ground and excited states: Charge-shift mechanism introduced by counter anion shift

Shmuel Zilberg

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The origin of the lowest triplet states - locally excited or charge shifted (T_LEvs. T_CS) - is a key point in the discussion of the charge shift phenomena of 9-mesityl-10-methylacridinium (see Fukuzumi et al. Phys. Chem. Chem. Phys., 2008, 10, 5159 vs. Benniston et al., Phys. Chem. Chem. Phys., 2008, 10, 5156). Coordination of the anion on the mesityl moiety provides the effective stabilization of the charge-shifted state.

Original language	English
Pages (from-to)	10292-10294
Number of pages	3
Journal	Physical Chemistry Chemical Physics
Volume	12
Issue number	35
DOIs	https://doi.org/10.1039/c0cp00491j
State	Published - 21 Sep 2010
Externally published	Yes

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N2 - The origin of the lowest triplet states - locally excited or charge shifted (TLEvs. TCS) - is a key point in the discussion of the charge shift phenomena of 9-mesityl-10-methylacridinium (see Fukuzumi et al. Phys. Chem. Chem. Phys., 2008, 10, 5159 vs. Benniston et al., Phys. Chem. Chem. Phys., 2008, 10, 5156). Coordination of the anion on the mesityl moiety provides the effective stabilization of the charge-shifted state.

AB - The origin of the lowest triplet states - locally excited or charge shifted (TLEvs. TCS) - is a key point in the discussion of the charge shift phenomena of 9-mesityl-10-methylacridinium (see Fukuzumi et al. Phys. Chem. Chem. Phys., 2008, 10, 5159 vs. Benniston et al., Phys. Chem. Chem. Phys., 2008, 10, 5156). Coordination of the anion on the mesityl moiety provides the effective stabilization of the charge-shifted state.

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JO - Physical Chemistry Chemical Physics

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Electronic structure of 9-mesityl-10-methylacridinium in ground and excited states: Charge-shift mechanism introduced by counter anion shift

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