Effect of ligands on reactivity of metal cations towards the hydrated electron. Part 1. - The effect of ethylenediaminetetraacetic acid

M. Anbar; D. Meyerstein

doi:10.1039/TF9696501812

Effect of ligands on reactivity of metal cations towards the hydrated electron. Part 1. - The effect of ethylenediaminetetraacetic acid

M. Anbar
, D. Meyerstein

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The specific rates of reaction of the hydrated electron with 31 EDTA complexes have been measured. EDTA normally decreases by several orders of magnitude the rate of reaction of a given metal cation with ^e- _aq relative to the rate of reaction of ^e-_aq with the corresponding aquo complex. The results are discussed in terms of different theories for outer sphere reactions; not all the results can be explained by the Marcus theory for hydrated electron reactions.

Original language	English
Pages (from-to)	1812-1817
Number of pages	6
Journal	Transactions of the Faraday Society
Volume	65
DOIs	https://doi.org/10.1039/TF9696501812
State	Published - 1969
Externally published	Yes

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title = "Effect of ligands on reactivity of metal cations towards the hydrated electron. Part 1. - The effect of ethylenediaminetetraacetic acid",

abstract = "The specific rates of reaction of the hydrated electron with 31 EDTA complexes have been measured. EDTA normally decreases by several orders of magnitude the rate of reaction of a given metal cation with e- aq relative to the rate of reaction of e-aq with the corresponding aquo complex. The results are discussed in terms of different theories for outer sphere reactions; not all the results can be explained by the Marcus theory for hydrated electron reactions.",

author = "M. Anbar and D. Meyerstein",

year = "1969",

doi = "10.1039/TF9696501812",

language = "אנגלית",

volume = "65",

pages = "1812--1817",

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T1 - Effect of ligands on reactivity of metal cations towards the hydrated electron. Part 1. - The effect of ethylenediaminetetraacetic acid

AU - Anbar, M.

AU - Meyerstein, D.

PY - 1969

Y1 - 1969

N2 - The specific rates of reaction of the hydrated electron with 31 EDTA complexes have been measured. EDTA normally decreases by several orders of magnitude the rate of reaction of a given metal cation with e- aq relative to the rate of reaction of e-aq with the corresponding aquo complex. The results are discussed in terms of different theories for outer sphere reactions; not all the results can be explained by the Marcus theory for hydrated electron reactions.

AB - The specific rates of reaction of the hydrated electron with 31 EDTA complexes have been measured. EDTA normally decreases by several orders of magnitude the rate of reaction of a given metal cation with e- aq relative to the rate of reaction of e-aq with the corresponding aquo complex. The results are discussed in terms of different theories for outer sphere reactions; not all the results can be explained by the Marcus theory for hydrated electron reactions.

UR - https://www.scopus.com/pages/publications/0014536045

U2 - 10.1039/TF9696501812

DO - 10.1039/TF9696501812

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AN - SCOPUS:0014536045

SN - 0014-7672

VL - 65

SP - 1812

EP - 1817

JO - Transactions of the Faraday Society

JF - Transactions of the Faraday Society

ER -

Effect of ligands on reactivity of metal cations towards the hydrated electron. Part 1. - The effect of ethylenediaminetetraacetic acid

Abstract

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