Cyclophosphates as ligands for cobalt(III) in water

Michael Montag; Christopher R. Clough; Peter Müller; Christopher C. Cummins

doi:10.1039/c0cc04342g

Cyclophosphates as ligands for cobalt(III) in water

Michael Montag, Christopher R. Clough, Peter Müller, Christopher C. Cummins

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Examination of cyclotriphosphate and cyclotetraphosphate as ligands for Co(III) in aqueous solutions revealed that cyclotetraphosphate affords stable complexes as a hemilabile ligand, while cyclotriphosphate exhibits facile hydrolysis.

Original language	English
Pages (from-to)	662-664
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	2
DOIs	https://doi.org/10.1039/c0cc04342g
State	Published - 14 Dec 2011
Externally published	Yes

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title = "Cyclophosphates as ligands for cobalt(III) in water",

abstract = "Examination of cyclotriphosphate and cyclotetraphosphate as ligands for Co(III) in aqueous solutions revealed that cyclotetraphosphate affords stable complexes as a hemilabile ligand, while cyclotriphosphate exhibits facile hydrolysis.",

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AU - Montag, Michael

AU - Clough, Christopher R.

AU - Müller, Peter

AU - Cummins, Christopher C.

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Y1 - 2011/12/14

N2 - Examination of cyclotriphosphate and cyclotetraphosphate as ligands for Co(III) in aqueous solutions revealed that cyclotetraphosphate affords stable complexes as a hemilabile ligand, while cyclotriphosphate exhibits facile hydrolysis.

AB - Examination of cyclotriphosphate and cyclotetraphosphate as ligands for Co(III) in aqueous solutions revealed that cyclotetraphosphate affords stable complexes as a hemilabile ligand, while cyclotriphosphate exhibits facile hydrolysis.

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JO - Chemical Communications

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Cyclophosphates as ligands for cobalt(III) in water

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