Cleavage of an Ether Bond via β‐Elimination of Ethanol from [(H2O)5CrCH2CH2OC2H5]2+ in Aqueous Solutions; A Pulse Radiolysis Study

Haim Cohen; Dan Meyerstein

doi:10.1002/anie.198507791

Cleavage of an Ether Bond via β‐Elimination of Ethanol from [(H₂O)₅CrCH₂CH₂OC₂H₅]²⁺ in Aqueous Solutions; A Pulse Radiolysis Study

Haim Cohen, Dan Meyerstein

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Abstract

β‐Elimination with cleavage of an ether bond has been observed in studies with the title compound. The rate constant for this reaction (4.6 × 10³ M⁻¹ s⁻¹) is similar to that for the elimination of the β‐OH group from the analogous CH₂C(CH₃)₂OH complex and related compounds. (Formula Presented.)

Original language	English
Pages (from-to)	779-781
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	24
Issue number	9
DOIs	https://doi.org/10.1002/anie.198507791
State	Published - Sep 1985
Externally published	Yes

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abstract = "β‐Elimination with cleavage of an ether bond has been observed in studies with the title compound. The rate constant for this reaction (4.6 × 103 M−1 s−1) is similar to that for the elimination of the β‐OH group from the analogous CH2C(CH3)2OH complex and related compounds. (Formula Presented.)",

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AB - β‐Elimination with cleavage of an ether bond has been observed in studies with the title compound. The rate constant for this reaction (4.6 × 103 M−1 s−1) is similar to that for the elimination of the β‐OH group from the analogous CH2C(CH3)2OH complex and related compounds. (Formula Presented.)

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Cleavage of an Ether Bond via β‐Elimination of Ethanol from [(H₂O)₅CrCH₂CH₂OC₂H₅]²⁺ in Aqueous Solutions; A Pulse Radiolysis Study

Abstract

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