Charge-transfer complexes of iodine and inorganic anions in solution

Dan Meyerstein; Avner Treinin

doi:10.1039/tf9635901114

Charge-transfer complexes of iodine and inorganic anions in solution

Dan Meyerstein
, Avner Treinin

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N^-₃. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.

Original language	English
Pages (from-to)	1114-1120
Number of pages	7
Journal	Transactions of the Faraday Society
Volume	59
DOIs	https://doi.org/10.1039/tf9635901114
State	Published - 1963
Externally published	Yes

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10.1039/tf9635901114

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title = "Charge-transfer complexes of iodine and inorganic anions in solution",

abstract = "In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.",

author = "Dan Meyerstein and Avner Treinin",

year = "1963",

doi = "10.1039/tf9635901114",

language = "אנגלית",

volume = "59",

pages = "1114--1120",

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T1 - Charge-transfer complexes of iodine and inorganic anions in solution

AU - Meyerstein, Dan

AU - Treinin, Avner

PY - 1963

Y1 - 1963

N2 - In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.

AB - In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.

UR - https://www.scopus.com/pages/publications/37049053372

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DO - 10.1039/tf9635901114

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AN - SCOPUS:37049053372

SN - 0014-7672

VL - 59

SP - 1114

EP - 1120

JO - Transactions of the Faraday Society

JF - Transactions of the Faraday Society

ER -

Charge-transfer complexes of iodine and inorganic anions in solution

Abstract

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