TY - JOUR
T1 - Charge-transfer complexes of iodine and inorganic anions in solution
AU - Meyerstein, Dan
AU - Treinin, Avner
PY - 1963
Y1 - 1963
N2 - In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.
AB - In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.
UR - http://www.scopus.com/inward/record.url?scp=37049053372&partnerID=8YFLogxK
U2 - 10.1039/tf9635901114
DO - 10.1039/tf9635901114
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AN - SCOPUS:37049053372
SN - 0014-7672
VL - 59
SP - 1114
EP - 1120
JO - Transactions of the Faraday Society
JF - Transactions of the Faraday Society
ER -