Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Steven J. Visco; Vitaliy Y. Nimon; Alexei Petrov; Kirill Pridatko; Nikolay Goncharenko; Eugene Nimon; Lutgard De Jonghe; Yury M. Volfkovich; Daniil A. Bograchev

doi:10.1007/s10008-014-2427-x

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Steven J. Visco, Vitaliy Y. Nimon, Alexei Petrov, Kirill Pridatko, Nikolay Goncharenko, Eugene Nimon, Lutgard De Jonghe, Yury M. Volfkovich, Daniil A. Bograchev

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

The extremely high theoretical energy density of the lithium-oxygen couple makes it very attractive for next-generation battery development. However, there are a number of challenging technical hurdles that must be addressed for Li-Air batteries to become a commercial reality. In this article, we demonstrate how the invention of water-stable, solid electrolyte-protected lithium electrodes solves many of these issues and paves the way for the development of aqueous and nonaqueous Li-Air batteries with unprecedented energy densities. We also show data for fully packaged Li-Air cells that achieve more than 800 Wh/kg.

Original language	English
Pages (from-to)	1443-1456
Number of pages	14
Journal	Journal of Solid State Electrochemistry
Volume	18
Issue number	5
DOIs	https://doi.org/10.1007/s10008-014-2427-x
State	Published - May 2014
Externally published	Yes

Keywords

Air
Battery
LATP
Lithium
PLE
Protected lithium electrode
Solid electrolyte

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10.1007/s10008-014-2427-x

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title = "Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes",

abstract = "The extremely high theoretical energy density of the lithium-oxygen couple makes it very attractive for next-generation battery development. However, there are a number of challenging technical hurdles that must be addressed for Li-Air batteries to become a commercial reality. In this article, we demonstrate how the invention of water-stable, solid electrolyte-protected lithium electrodes solves many of these issues and paves the way for the development of aqueous and nonaqueous Li-Air batteries with unprecedented energy densities. We also show data for fully packaged Li-Air cells that achieve more than 800 Wh/kg.",

keywords = "Air, Battery, LATP, Lithium, PLE, Protected lithium electrode, Solid electrolyte",

author = "Visco, {Steven J.} and Nimon, {Vitaliy Y.} and Alexei Petrov and Kirill Pridatko and Nikolay Goncharenko and Eugene Nimon and {De Jonghe}, Lutgard and Volfkovich, {Yury M.} and Bograchev, {Daniil A.}",

note = "Funding Information: This work was funded in part by the ARPA-E of the U.S. Department of Energy and by the U.S. Army CERDEC. The authors also acknowledge the participation of V. Loginova in the experimental work and helpful discussions with Dr. P.N. Ross of the Lawrence Berkeley National Laboratory in Berkeley, CA. ",

year = "2014",

month = may,

doi = "10.1007/s10008-014-2427-x",

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volume = "18",

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journal = "Journal of Solid State Electrochemistry",

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AU - Visco, Steven J.

AU - Nimon, Vitaliy Y.

AU - Petrov, Alexei

AU - Pridatko, Kirill

AU - Goncharenko, Nikolay

AU - Nimon, Eugene

AU - De Jonghe, Lutgard

AU - Volfkovich, Yury M.

AU - Bograchev, Daniil A.

N1 - Funding Information: This work was funded in part by the ARPA-E of the U.S. Department of Energy and by the U.S. Army CERDEC. The authors also acknowledge the participation of V. Loginova in the experimental work and helpful discussions with Dr. P.N. Ross of the Lawrence Berkeley National Laboratory in Berkeley, CA.

PY - 2014/5

Y1 - 2014/5

N2 - The extremely high theoretical energy density of the lithium-oxygen couple makes it very attractive for next-generation battery development. However, there are a number of challenging technical hurdles that must be addressed for Li-Air batteries to become a commercial reality. In this article, we demonstrate how the invention of water-stable, solid electrolyte-protected lithium electrodes solves many of these issues and paves the way for the development of aqueous and nonaqueous Li-Air batteries with unprecedented energy densities. We also show data for fully packaged Li-Air cells that achieve more than 800 Wh/kg.

AB - The extremely high theoretical energy density of the lithium-oxygen couple makes it very attractive for next-generation battery development. However, there are a number of challenging technical hurdles that must be addressed for Li-Air batteries to become a commercial reality. In this article, we demonstrate how the invention of water-stable, solid electrolyte-protected lithium electrodes solves many of these issues and paves the way for the development of aqueous and nonaqueous Li-Air batteries with unprecedented energy densities. We also show data for fully packaged Li-Air cells that achieve more than 800 Wh/kg.

KW - Air

KW - Battery

KW - LATP

KW - Lithium

KW - PLE

KW - Protected lithium electrode

KW - Solid electrolyte

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VL - 18

SP - 1443

EP - 1456

JO - Journal of Solid State Electrochemistry

JF - Journal of Solid State Electrochemistry

IS - 5

ER -

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

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Keywords

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