@inproceedings{7a51603af85a4c5491dc7b2a7b9f1c50,
title = "An electrochemical and spectroelectrochemical study of Ln(II) (Ln = Sm, Eu, Yb) species in NaCl-2CsCl melt",
abstract = "The behavior of lanthanide (samarium, europium and ytterbium) chloride species in NaCl-2CsCl eutectic based melts was studied between 823-1023 K employing cyclic voltammetry, high temperature electronic absorption spectroscopy and spectroelectrochemistry. Diffusion coefficients of the lanthanide chloro-species, formal standard red-ox potentials and thermodynamics of the formation of LnCl3 from the corresponding dichlorides in the melts were determined. A series of spectroelectrochemical experiments was performed to study cathodic reduction of Ln(III) ions under potentiostatic conditions. Sm(III), Eu(III) and Yb(III) species in NaCl-2CsCl melts can be reduced by metallic zirconium and this reaction was investigated using high temperature spectroscopy.",
author = "Volkovich, {V. A.} and Ivanov, {A. B.} and Sobolev, {A. A.} and Vasin, {B. D.} and Griffiths, {T. R.}",
note = "Publisher Copyright: Copyright {\textcopyright} 2014 by The Electrochemical Society. All rights reserved.; 19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting ; Conference date: 05-10-2014 Through 09-10-2014",
year = "2014",
doi = "10.1149/06404.0617ecst",
language = "אנגלית",
series = "ECS Transactions",
publisher = "Electrochemical Society Inc.",
number = "4",
pages = "617--634",
editor = "{De Long}, {Hugh C.} and Reichert, {W. Matthew} and Trulove, {Paul C.} and Haverhals, {Luke M.} and Minoru Mizuhata and Mantz, {Robert A.} and Adriana Ispas and Andreas Bund",
booktitle = "Molten Salts and Ionic Liquids 19",
edition = "4",
}