TY - JOUR
T1 - Absorption spectra of NO3- in solution
AU - Meyerstein, Dan
AU - Treinin, Avner
PY - 1961
Y1 - 1961
N2 - The nature of the electronic transitions, responsible for the absorption bands of NO3- in solution, is discussed. Environmental effects were studied to ascertain the type of transition responsible for the high intensity band. The effects detected on this band are entirely different from that displayed by electron-transfer band and hence it is assigned to internal transition, which is probably π→π. The effects studied are due to change of temperature, solvent and addition of various substances, mainly electrolytes. Ionic effects are discussed in view of the various types of ionic association. It is suggested that H-bonding plays a prominent role in the mechanism of these effects.
AB - The nature of the electronic transitions, responsible for the absorption bands of NO3- in solution, is discussed. Environmental effects were studied to ascertain the type of transition responsible for the high intensity band. The effects detected on this band are entirely different from that displayed by electron-transfer band and hence it is assigned to internal transition, which is probably π→π. The effects studied are due to change of temperature, solvent and addition of various substances, mainly electrolytes. Ionic effects are discussed in view of the various types of ionic association. It is suggested that H-bonding plays a prominent role in the mechanism of these effects.
UR - http://www.scopus.com/inward/record.url?scp=0000098090&partnerID=8YFLogxK
U2 - 10.1039/TF9615702104
DO - 10.1039/TF9615702104
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AN - SCOPUS:0000098090
SN - 0014-7672
VL - 57
SP - 2104
EP - 2112
JO - Transactions of the Faraday Society
JF - Transactions of the Faraday Society
ER -