A novel formyl complex [(H2O)5CrCHO]2+. A pulse radiolysis study

Haim Cohen; Dan Meyerstein; Alan J. Shusterman; Mathania Weiss

doi:10.1039/c39850000424

A novel formyl complex [(H²O)₅CrCHO]²⁺. A pulse radiolysis study

Haim Cohen, Dan Meyerstein, Alan J. Shusterman, Mathania Weiss

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Abstract

The formyl complex [(H₂O)₅CrCHO]²⁺ is formed in aqueous solution via the reaction sequence: Cr²⁺(aq.) + ·CH(OH)₂ → [(H₂O)₅CrCH(OH) ₂]²⁺ → [(H₂O)₅CrCHO ⁺²] + H₂O, and reduces formaldehyde (k = 1 mol ^-1 dm³ s^-1), yielding CO + CH₃OH; the spectra of [(H₂O)₅CrCH(OH)₂]²⁺ and [(H₂O)₅CrCHO]²⁺ are reported.

Original language	English
Pages (from-to)	424-425
Number of pages	2
Journal	Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/c39850000424
State	Published - 1985
Externally published	Yes

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title = "A novel formyl complex [(H2O)5CrCHO]2+. A pulse radiolysis study",

abstract = "The formyl complex [(H2O)5CrCHO]2+ is formed in aqueous solution via the reaction sequence: Cr2+(aq.) + ·CH(OH)2 → [(H2O)5CrCH(OH) 2]2+ → [(H2O)5CrCHO +2] + H2O, and reduces formaldehyde (k = 1 mol -1 dm3 s-1), yielding CO + CH3OH; the spectra of [(H2O)5CrCH(OH)2]2+ and [(H2O)5CrCHO]2+ are reported.",

author = "Haim Cohen and Dan Meyerstein and Shusterman, {Alan J.} and Mathania Weiss",

year = "1985",

doi = "10.1039/c39850000424",

language = "אנגלית",

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journal = "Chemical Communications",

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T1 - A novel formyl complex [(H2O)5CrCHO]2+. A pulse radiolysis study

AU - Cohen, Haim

AU - Meyerstein, Dan

AU - Shusterman, Alan J.

AU - Weiss, Mathania

PY - 1985

Y1 - 1985

N2 - The formyl complex [(H2O)5CrCHO]2+ is formed in aqueous solution via the reaction sequence: Cr2+(aq.) + ·CH(OH)2 → [(H2O)5CrCH(OH) 2]2+ → [(H2O)5CrCHO +2] + H2O, and reduces formaldehyde (k = 1 mol -1 dm3 s-1), yielding CO + CH3OH; the spectra of [(H2O)5CrCH(OH)2]2+ and [(H2O)5CrCHO]2+ are reported.

AB - The formyl complex [(H2O)5CrCHO]2+ is formed in aqueous solution via the reaction sequence: Cr2+(aq.) + ·CH(OH)2 → [(H2O)5CrCH(OH) 2]2+ → [(H2O)5CrCHO +2] + H2O, and reduces formaldehyde (k = 1 mol -1 dm3 s-1), yielding CO + CH3OH; the spectra of [(H2O)5CrCH(OH)2]2+ and [(H2O)5CrCHO]2+ are reported.

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SP - 424

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JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

A novel formyl complex [(H²O)₅CrCHO]²⁺. A pulse radiolysis study

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