Abstract
Reported herein is the successful use of the commercially available organic dye bromocresol green (compound 1) for high-performing and practical fluoride detection. This dye responds to fluoride anion with high selectivity (virtually no response to other halide anions), excellent sensitivity (limits of detection as low as 0.22 ppm) and rapid response times, and maintains functionality when it is adsorbed on filter paper. Mechanistic studies determined that the fluoride-induced colorimetric changes were due to intermolecular hydrogen bonding between compound 1 and fluoride. Finally, the broad applicability of this sensor was demonstrated through the colorimetric response of compound 1 – functionalized paper to fluoride in commercial mouthwash. These findings underscore compound 1’s potential as a practical and commercially viable fluoride sensor, in addition to compound 1’s better-known role as a colorimetric pH indicator.
Original language | English |
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Article number | 111944 |
Journal | Microchemical Journal |
Volume | 207 |
DOIs | |
State | Published - Dec 2024 |
Keywords
- Bromocresol green
- Colorimetric sensor
- Fluoride detection
- Paper-based sensor